CIESC Journal

• 化工学报 • 上一篇    下一篇

温度敏感性水凝胶的分子热力学模型

陆大年,胡英   

  1. 华东理工大学化学系!上海200237,华东理工大学化学系!上海200237
  • 出版日期:1995-10-25 发布日期:1995-10-25

MOLECULAR THERMODYNAMIC MODEL FOR TEMPERATURE-SENSITIVE HYDROGELS

Lu Danian and Hu Ying(Depart!tent of Chemistry, East China University of Science and Technology, Shanghai, 200253)   

  • Online:1995-10-25 Published:1995-10-25

摘要: 在Flory的物理缠结模型基础上,本文阐述了高分子凝胶网络中存在超短链及勾结链等非理想结构的可能性及其对凝胶溶胀性能的影响。从而进一步修改了弹性模型,并结合格子流体模型,提出了1个新的非离子凝胶热力学模型。该模型在解释凝胶相行为以及关联温度敏感性水凝胶的溶胀平衡曲线方面取得了良好效果。

Abstract: Possibility of non -Gaussian short chains and interlooping chains formed in gel-network, and their influence on swelling characteristics of gels are discussed on the basis of Florys physical -entanglement model. A new molecular thermodynamic theory for non -ionic gels basec on a lattic - fluid model and an elastic model is introduced in which the elastic contribution by the non -Gaussian short chains and interlooping chains is included. The theory can be used to describe various phase behaviors for temperature -sensitive gels. Satisfactory results art obtaind in the correlation of practical swelling equilibria.

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