CIESC Journal

• 化工学报 • 上一篇    下一篇

水合物生成和分解动力学研究现状

裘俊红,郭天民   

  1. 石油大学化工学部!北京102200,石油大学化工学部!北京102200
  • 出版日期:1995-12-25 发布日期:1995-12-25

THE STATUS OF THE KINETICS OF HYDRATE FORMATION AND DECOMPOSITION

Qiu Junhong and Guo Tianmin(Department of Chemical Engineering, University of Petroleum,Beijing 102200)   

  • Online:1995-12-25 Published:1995-12-25

摘要: 从微观动力学和宏观动力学的角度对水合物生成和分解动力学研究文献进行了分类、评述,着重点是水合物生成的微观机理和水合物晶体生长的宏观动力学.关于水合物生成的微观动力学,着重介绍3个比较完整的水合物生成机理以及相应的机理模型.关于水合物生成的宏观动力学,着重阐述加拿大Bishnoi实验室所取得的研究成果以及日本学者结合CO_2水合物处置法开展的CO_2水合物生成动力学研究工作.关于水合物分解,主要讨论水合物在受热、降压和抑制剂存在时的分解动力学.基于水合物生成和分解动力学的研究现状,指出了今后研究的8个重要方向.

Abstract: This paper reviews the literatures on the kinetics of hydrate formation and decomposition from the point of view of microscopic and macroscopic kinetics. The emphasis is on the microscopic mechanism for hydrate formation and the macroscopic kinetics of hydrate crystal growth. For the microscopic kinetics of hydrate formation, three mechanisms and the relevant models are reviewed. For the macroscopic kinetics, the research at Bishnois laboratory in Canada and the work associated with CO2 hydrate disposal in Japan on the kinetics of CO2 hydrate formation are briefly described. For the hydrate decomposition, the kinetics under thermal stimulation, depressurization, and in the presence of inhibitors are discussed. Based on the current status of the hydrate kinetics research, the authors suggest eight important aspects for future hydrate kinetics research.

中图分类号: