CIESC Journal

• Volume 7 • 上一篇    下一篇

Dimension Reduction Method in Thermodynamics of Multireaction Systems*
Residual Properties, Property Changes of Mixing and Excess Properties Relations

李浩然a; 陈志荣b; 韩世钧a   

  1. a Department of Chemistry, Zhejiang University, Hangzhou 310027,China
    b Department of Chemical Engineering, Zhejiang University, Hangzhou 310027
  • 收稿日期:1997-09-22 修回日期:1900-01-01 出版日期:1999-03-28 发布日期:1999-03-28
  • 通讯作者: 李浩然

Dimension Reduction Method in Thermodynamics of Multireaction Systems*
Residual Properties, Property Changes of Mixing and Excess Properties Relations

Li Haorana; Chen Zhirongb; Han Shijuna   

  1. a Department of Chemistry, Zhejiang University, Hangzhou 310027,China
    b Department of Chemical Engineering, Zhejiang University, Hangzhou 310027
  • Received:1997-09-22 Revised:1900-01-01 Online:1999-03-28 Published:1999-03-28
  • Contact: Li Haoran

摘要: Based on the fundamental thermodynamic principle the relationships of the residual
properties, the property changes of mixing and the excess properties between the
hypothetical solution of unreacted independent species and the equilibrated solution of
actual species have been established. The hypothetical solution provides a way of reducing
the dimensionality of problem and simplifying the analysis.

关键词: thermodynamics;phase equilibrium;multireaction

Abstract: Based on the fundamental thermodynamic principle the relationships of the residual
properties, the property changes of mixing and the excess properties between the
hypothetical solution of unreacted independent species and the equilibrated solution of
actual species have been established. The hypothetical solution provides a way of reducing
the dimensionality of problem and simplifying the analysis.

Key words: thermodynamics, phase equilibrium, multireaction