钟理; 郭江海; 吕扬效; 李小莹; 李琼; 高桂田
Zhong Li; Guo Jianghai; Lu Yangxiao; Li Xiaoying; Li Qiong; Gao Guitian
摘要: A kinetic model has been developed for the degradation of organic pollutants concerning
with hydroperoxide ion as the initial step for generation of hydroxyl radical and its
subsequent reaction mechanisms. Rate equations were derived for depletion of ozone and
pollutants in the peroxone oxidation process using ozone and hydrogen peroxide as combined
oxidants. Kinetic data obtained experimentally from the hydrogen peroxide-ozone reaction
and peroxone oxidation of nitrobenzene were analyzed by using the proposed rate equations.