CIESC Journal

• Volume 7 • 上一篇    下一篇

A Population Balance Model for Disperse Systems: Particle Size Distribution in Suspension Polymerization

陈中; Werner Pauer; H.-U.Moritz; Jan Pruss; Hans-JoachimWarnecke   

  1. Cbemical Engineering, University of Paderborn, Paderborn 33098, Germany
  • 收稿日期:1998-12-25 修回日期:1900-01-01 出版日期:1999-12-28 发布日期:1999-12-28
  • 通讯作者: 陈中

A Population Balance Model for Disperse Systems: Particle Size Distribution in Suspension
Polymerization

CHEN Zhong; Werner Pauer; H.-U.Moritz; Jan Pruss; Hans-JoachimWarnecke   

  1. Cbemical Engineering, University of Paderborn, Paderborn 33098, Germany
  • Received:1998-12-25 Revised:1900-01-01 Online:1999-12-28 Published:1999-12-28
  • Contact: CHEN Zhong

摘要: On the basis of population balance a mathematical model is developed to describe the
formation of polymer partlcle in styrene suspension polymerization. The characteristics of
coalescence and breakage of droplets and the gel effect are analyzed in particular.
Parameters of the models are esthnztted by experimental. on reaction conversion and
particle size distributlon. The results show that the model is suitable for predicting
polymerization processes.

关键词: 悬浮液聚合;种群平衡模型;分散体系;粒度分布;聚合工艺

Abstract: On the basis of population balance a mathematical model is developed to describe the
formation of polymer partlcle in styrene suspension polymerization. The characteristics of
coalescence and breakage of droplets and the gel effect are analyzed in particular.
Parameters of the models are esthnztted by experimental. on reaction conversion and
particle size distributlon. The results show that the model is suitable for predicting
polymerization processes.

Key words: population balance model, styrene, suspension polymerization, particle size distribution