CIESC Journal

• 化工学报 • 上一篇    下一篇

多相光化学反应器的辐射能传递模型

戴智铭,朱中南,陈爱平,古宏晨   

  1. 华东理工大学联合化学反应工程研究所!上海200237,华东理工大学联合化学反应工程研究所!上海200237,华东理工大学技术化学物理研究所!上海200237,华东理工大学技术化学物理研究所!上海200237
  • 出版日期:2001-02-25 发布日期:2001-02-25

RADIANT ENERGY TRANSFER MODEL IN MULTIPHASE PHOTOCHEMICAL REACTORS

DAI Zhiming and ZHU Zhongnan (UNILAB Research Center of Chemical Reaction Engineering, East China University of Science and Technology, Shanghai?200237,China)CHEN Aiping and GU Hongchen (Institute of Technical Chemistry and Physics,East China Univ   

  • Online:2001-02-25 Published:2001-02-25

摘要: 以双通量模型为基础模拟多相光化学反应器中的辐射能传递行为 ,考虑透过光催化剂颗粒的光子总数修正了双通量模型 ,采用比较简单的模型说明了多相光化学反应器内量纲 1光辐射能分布和光催化剂的量纲 1吸收光子总数分布 ,举例讨论了半导体超细粉末二氧化钛为光催化剂的气固相光化学反应器在不同光催化剂粒径、不同反应器厚度条件下反应器内量纲 1光辐射能分布和光催化剂的量纲 1吸收光子总数分布

Abstract: On the basis of the two-flux model of radiative transfer in photochemical reactor, the model was extended by considering light transmission passing through the photocatalyst, and reflection and absorption of light by the photocatalyst in the plane parallel-plate reactor. The extended model showed the dimensionless radiation intensity distribution and the dimensionless total radiative energy absorption rate in heterogeneous photoreactor. Semiconductor ultrafine TiO 2 power was widely used as the photocatalyst in heterogeneous photochemical reactor for environmental control. In order to show the usefulness of this simple method, the effects of TiO 2 power diameter and reactor depth on the dimensionless radiation intensity distribution and on the dimensionless total radiative energy absorption rate in gas-solid heterogeneous photocatalytic reactor were illustrated. The model explained that it was necessary to select reasonable reactor depth, particle diameter and density on semiconductor heterogeneous photoreactor designed.

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