CIESC Journal

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丙烯氯醇化反应过程的模型化

吴国斌; 周兴贵; 袁渭康   

  1. 华东理工大学联合化学反应工程研究所
  • 出版日期:2001-06-25 发布日期:2001-06-25

MATHEMATICAL MODEL OF PROPYLENE CHLOROHYDRIN ACTION PROCESS

WU Guobin;ZHOU Xinggui;YUAN Weikang   

  • Online:2001-06-25 Published:2001-06-25

摘要: 将单塔自然液相循环的丙烯氯醇化反应器视为两个串联的鼓泡塔 ,在两塔分别进行溶氯和氯醇化反应 .在对反应机理和宏观动力学进行探讨的基础上 ,建立了反应器的一维定态模型 .通过流程模拟 ,研究了操作参数对反应结果的影响 .结果表明 ,所建立的一维定态模型能正确描述重要操作参数的影响规律

Abstract: A model for the propylene chlorohydrin action process in propylene oxide plant is developed.The reactor featuring natural liquid circulating and forced gas recycling is considered as two bubble reactors connected in series,the first one being the chlorine absorber and the second one the chlorohydrination reactor.The reaction is of Fyvie mechanism and the mass transfer is characterized by simultaneous adsorption of two gases with the reactions carried out in the liquid phase.Side reaction occuring in the gas phase is also considered.The gas is assumed to be plug flow and the liquid complete mixing flow in both of the two reactors.The influence of the operating variables on conversion and yield is investigated by process simulation.The model presented is found to be successful in describing the static behavior of the reactor.It is demonstrated that low temperature,low feed gas ratio,low propylene chlorohydrin concentration and high recycle gas velocity are all favorable to improving the yield.