徐铜文; 杨伟华; 何柄林
a Department of Applied Chemistry, University of Science and Technology of China, Hefei
230026, China
b The State Key Laboratory of Functional Polymeric Materials for Adsorption and Separation,
Nankai University, Tianjin 300071, China
XU Tongwen; YANG Weihua; HE Binglin
摘要: Ionic partition equilibrium in charged membrane immersed in solution of single electrolyte
with mono valence or multi-valence is systematically investigated and several expressions
are established for determination of partition coefficients. On this basis, the effects of
the ratio of membrane charge density to bulk electrolyte solution concentration, the charge
sign and valence of electrolyte ions and the type of membrane on the partition equilibrium
were analyzed and simulated within chosen parameters. It is revealed that ion partition is
not related solely with the respective concentrations but also definitely with the
concentration ratio of fixed group to bulk solution in addition to the charge sign and the
valence. For a counterion, the partition coefficient increases with this ratio and the
valence; while for a coion, the partition coefficient decreases with this ratio and the
valence. The theoretical calculations were compared with the experimental data and a good
agreement was observed.