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黄芩甙在EOPO/盐双水相系统中的分配系数测定及关联

李伟a; 朱自强b   

  1. a College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310027,
    China
    b Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027,
    China
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2002-12-28 发布日期:2002-12-28
  • 通讯作者: 李伟

Measurement and Correlation of Partition Coefficients of Baicalin in EOPO/Salt Aqueous Two
-Phase Systems

LI Weia; ZHU Ziqiangb   

  1. a College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310027,
    China
    b Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027,
    China
  • Received:1900-01-01 Revised:1900-01-01 Online:2002-12-28 Published:2002-12-28
  • Contact: LI Wei

摘要: The partition coefficients of baicalin were measured in ethylene oxide and propylene oxide
(EOPO)/salt aqueous two-phase systemsat 298.15K. It was found that most of baicalin
partitioned into EOPO-rich phase. The partition coefficients of baicalin varied from 10 to
120.The effect of various factors, including tie-line length, salt composition, molecular
weight of EOPO, and solution pH, on the partition behaviorwas investigated in EOPO/salt
systems. Furthermore the partition coefficients of baicalin were correlated using the
modified Diamond-Hsumodel. Good agreement with experimental data is obtained. The average
relative deviations are less than 5.0%.

关键词: aqueous two-phase system;ethylene oxide and proplene oxide;partition coefficient; baiealin

Abstract: The partition coefficients of baicalin were measured in ethylene oxide and propylene oxide
(EOPO)/salt aqueous two-phase systemsat 298.15K. It was found that most of baicalin
partitioned into EOPO-rich phase. The partition coefficients of baicalin varied from 10 to
120.The effect of various factors, including tie-line length, salt composition, molecular
weight of EOPO, and solution pH, on the partition behaviorwas investigated in EOPO/salt
systems. Furthermore the partition coefficients of baicalin were correlated using the
modified Diamond-Hsumodel. Good agreement with experimental data is obtained. The average
relative deviations are less than 5.0%.

Key words: aqueous two-phase system, ethylene oxide and proplene oxide, partition coefficient, baiealin