金属担载分子筛对含硫模型化合物和含硫烃的催化裂化脱硫反应的影响

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金属担载分子筛对含硫模型化合物和含硫烃的催化裂化脱硫反应的影响

申宝剑; 李海丽; 李会峰; 鲍晓军; 周小虹

State Key Laboratory of Heavy Oil Processing, The Key Laboratory of Catalysis, China
National Petroleum Co.,and Faculty of Chemical Engineering, University of Petroleum,
Beijing,102249, China

收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2003-12-28 发布日期:2003-12-28
通讯作者: 申宝剑

Influence of Molecular Sieve Supported Metal Oxides on the Desulfurization in Catalytic
Cracking of Sulfur-containing Model Compounds and Hydrocarbons

SHEN Baojian; LI Haili; LI Huifeng; BAO Xiaojun; ZHOU Xiaohong

State Key Laboratory of Heavy Oil Processing, The Key Laboratory of Catalysis, China
National Petroleum Co.,and Faculty of Chemical Engineering, University of Petroleum,
Beijing,102249, China

Received:1900-01-01 Revised:1900-01-01 Online:2003-12-28 Published:2003-12-28
Contact: SHEN Baojian

摘要/Abstract

摘要： Zn, La, Zr, Sn and Ti loaded molecular sieves were prepared by impregnation method.
Conversions of benzothiophene and dibenzothiophene over the metal oxides modified ultra
stable zeolite Y(USY), ZSM-5, β and MSU-2 molecular sieve catalysts were investigated by
means of micro-activity test (MAT) experiments. The results showed that Zn and La loaded
catalysts were better than the other metals, and ZSM-5 with lower SiO2/Al2O3 mole ratio
showed better results than those with higher SiO2/Al2O3 as far as desulfurization reaction
is considered. A comparison of the desulfurization activities of the La/Zn-USY catalyst
with USY catalyst indicated that the bimetal loaded USY catalyst gave good products
selectivity when sulfur containing heavy oil was used as the feedstock. The sulfur content
in gasoline fraction was decreased by 25%, and there was no loss in the Research Octane
Number.

关键词: desulfurization;catalytic cracking;metal oxide;zeolite;hydrocarbons

Abstract: Zn, La, Zr, Sn and Ti loaded molecular sieves were prepared by impregnation method.
Conversions of benzothiophene and dibenzothiophene over the metal oxides modified ultra
stable zeolite Y(USY), ZSM-5, β and MSU-2 molecular sieve catalysts were investigated by
means of micro-activity test (MAT) experiments. The results showed that Zn and La loaded
catalysts were better than the other metals, and ZSM-5 with lower SiO2/Al2O3 mole ratio
showed better results than those with higher SiO2/Al2O3 as far as desulfurization reaction
is considered. A comparison of the desulfurization activities of the La/Zn-USY catalyst
with USY catalyst indicated that the bimetal loaded USY catalyst gave good products
selectivity when sulfur containing heavy oil was used as the feedstock. The sulfur content
in gasoline fraction was decreased by 25%, and there was no loss in the Research Octane
Number.

Key words: desulfurization, catalytic cracking, metal oxide, zeolite, hydrocarbons

申宝剑, 李海丽, 李会峰, 鲍晓军, 周小虹. 金属担载分子筛对含硫模型化合物和含硫烃的催化裂化脱硫反应的影响[J]. CIESC Journal.

SHEN Baojian, LI Haili, LI Huifeng, BAO Xiaojun, ZHOU Xiaohong. Influence of Molecular Sieve Supported Metal Oxides on the Desulfurization in Catalytic
Cracking of Sulfur-containing Model Compounds and Hydrocarbons[J]. .

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金属担载分子筛对含硫模型化合物和含硫烃的催化裂化脱硫反应的影响

Influence of Molecular Sieve Supported Metal Oxides on the Desulfurization in Catalytic
Cracking of Sulfur-containing Model Compounds and Hydrocarbons

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金属担载分子筛对含硫模型化合物和含硫烃的催化裂化脱硫反应的影响

Influence of Molecular Sieve Supported Metal Oxides on the Desulfurization in Catalytic Cracking of Sulfur-containing Model Compounds and Hydrocarbons

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Influence of Molecular Sieve Supported Metal Oxides on the Desulfurization in Catalytic
Cracking of Sulfur-containing Model Compounds and Hydrocarbons