CIESC Journal

• 催化、动力学与反应器 • 上一篇    下一篇

对二甲苯液相催化氧化动力学(Ⅱ)温度效应

谢刚;李希;牛俊峰   

  1. 浙江大学化学工程与生物工程学系,浙江 杭州 310027;浙江科技学院生物与化学工程系,浙江 杭州 310012

  • 出版日期:2003-07-25 发布日期:2003-07-25

KINETICS OF p-XYLENE LIQUID PHASE CATALYTIC OXIDATION(Ⅱ)TEMPERATURE EFFECT

XIE Gang;LI Xi;NIU Junfeng   

  • Online:2003-07-25 Published:2003-07-25

Abstract: p-Xylene liquid phase oxidation at different temperatures of 186—197℃ was carried out to investigate the temperature effect. The kinetics model developed in Part(Ⅰ) was used to fit the data.The rate constants obtained can be well represented by the Arrhenius relationship.The obtained activation energy of different reaction steps ranged from 54 kJ•mol-1 to 93kJ•mol-1, among them the activation energy of p-toluic acid to 4-carboxybenzaldehyde step was the highest (92.8kJ•mol-1) and that of 4-carboxybenzaldehyde to terephthalic acid step was the second(84.9kJ•mol-1).They are remarkably higher than the values of the other steps (54.94—67.53kJ•mol-1). This fact showed that oxidation of the second methyl group of p-xylene was more sensitive to the temperature variation than the first one.