CIESC Journal

• 催化、动力学与反应器 • 上一篇    下一篇

流向变换催化燃烧反应器的热波特性

牛学坤;李成岳;陈标华;周集义   

  1. 北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京 100029; 黎明化工研究院,河南 洛阳 471001

  • 出版日期:2003-08-25 发布日期:2003-08-25

CHARACTERISTICS OF THERAML WAVE OF REVERSE FLOW REACTOR FOR CATALYTIC COMBUSTION OF CONTAMINANTS

NIU Xuekun;LI Chengyue;CHEN Biaohua;ZHOU Jiyi   

  • Online:2003-08-25 Published:2003-08-25

摘要: 在小型中试装置上利用国产催化剂进行了含混合芳烃模拟工业废气的脱毒实验研究,在污染物浓度490~3920mg•m-3、换向周期15~60min、空速(2.4~9.6)×103h-1和气体流速0.340~1.359m•s-1的宽广范围内系统地考察了流向变换催化燃烧反应器的操作特性,特别是热波特性与操作参数如进料浓度、气速和换向周期之间的相互关系.结果表明,凡是影响一个周期内反应器热平衡的操作参数都有可能显著地影响反应段的温度水平.为这一类反应器的科学设计、优化操作和模型化研究奠定了中试基础.

Abstract: In a pilot scale reactor packed with a liter of catalyst the performance of a reverse flow reactor for catalytic combustion of typical industrial waste gas containing aromatics was systematically investigated. In a wide range over 490—3920mg•m-3 of contaminants concentration,15—60min of periodic duration,(2.4—9.6)×103 h-1 of space velocity and 0.340—1.359 m•s-1 of gas velocity,the influence of operating parameters such as the feed concentration of VOCs, the periodic duration and gas velocity on the characteristics of heat wave was studied. The results showed that the variation in the operation parameters which strongly influenced the heat balance of the reactor in a cycle would lead to a considerable change in the axial temperature profile of the reactor. This work provided the data for the design, operation and modeling of this kind of reactors on the pilot scale.