过氧化氢法制备二氧化氯的反应机理及动力学
CIESC Journal
• 催化、动力学与反应器 • 上一篇 下一篇
钱宇;陈赟;江燕斌;纪红兵
华南理工大学化工学院,广东 广州 510640
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REACTION MECHANISM AND DYNAMICS OF H2O2-BASED CHLORINE DIOXIDE PRODUCTION
QIAN Yu;CHEN Yun;JIANG Yanbin;JI Hongbing
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Abstract: To develop a cleaner production process of H2O2-based chlorine dioxide, this paper presents a study on reaction mechanism and dynamics of the process.It is shown that a complex H2ClO2-ClO3 exists as an intermediate in the process.A rational reaction process is proposed, which unifies several reaction mechanisms reported by different researchers in a wider range of reaction temperature.A theoretical model of the dynamics is presented, and parameters of the model are experimentally estimated and verified.
钱宇;陈赟;江燕斌;纪红兵.
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https://hgxb.cip.com.cn/CN/Y2004/V55/I10/1719