Pd/Fe双金属对水中m-二氯苯的催化脱氯
CIESC Journal
• 能源和环境工程 • 上一篇 下一篇
周红艺;徐新华;汪大翚
浙江工业大学生物与环境工程学院,浙江 杭州 310032;浙江大学环境工程系,浙江 杭州 310027
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CATALYTIC DECHLORINATION OF m-DCB IN WATER BY Pd/Fe
ZHOU Hongyi;XU Xinhua;WANG Dahui
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Abstract: Pd/Fe bimetallic catalysts were synthesized via chemical deposition and used to treat m-DCB.Batch experiments demonstrated that the Pd/Fe bimetallic particles could effectively dechlorinate m-DCB.The dechlorination efficiency reached 90% at a Pd/Fe loading ratio of 0.02% (mass) and metal to solution ratio 4g∶75ml in 90 min.Dechlorination was affected by several factors such as reaction temperature, pH, Pd/Fe ratio, and the induction of Pd/Fe catalysts.Chlorobenzene represents the partially stable dechlorinated intermediate in the generation of the final product (i.e., benzene), while part of m-DCB was dechlorinated to benzene directly.The dechlorination reaction was believed to take place mainly on the active surface sites of the Pd/Fe bimetallic particles via a pseudo-first order reaction, and the activation energy of this reaction was found to be 96.6 kJ8226;mol-1.
周红艺;徐新华;汪大翚.
ZHOU Hongyi;XU Xinhua;WANG Dahui.
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https://hgxb.cip.com.cn/CN/Y2004/V55/I11/1912