CIESC Journal

• 材料科学与工程 • 上一篇    下一篇

纳米γ-Fe2O3复合氧化物的制备与气敏性质

马丽景;林茂;闫涛;李英霞;黄小葳;陈霭璠;宋永吉   

  1. 北京化工大学理学院,北京100029;北京石油化工学院材料与化工学院,北京102617

  • 出版日期:2004-02-25 发布日期:2004-02-25

CATALYTZC AND GAS-SENSING PROPERTIES OF NANOSIZED γ-Fe2O3 COMPLEX OXIDE

MA Lijing;LIN Mao;YAN Tao;LI Yingxia;HUANG Xiaowei;CHEN Aifan;SONG Yongji   

  • Online:2004-02-25 Published:2004-02-25

摘要: 用溶胶-凝胶法制备了纳米γ-Fe2O3γ-Fe2O3/SiO2复合氧化物,用热重-差热分析 (TG-DTA)、X射线衍射 (XRD)、透射电镜 (TEM)和二次粒度分布对纳米粒子进行表征,并考察了γ-Fe2O3γ-Fe2O3/SiO2敏感材料对CO、H2、C2H4、C6H6等气体的敏感系数及其焙烧温度对敏感系数的影响,并选择了敏感材料对气体检测的最佳工作温度.结果表明,γ-Fe2O3/SiO2纳米复合氧化物中SiO2对提高γ-Fe2O3的相变温度、加强热稳定性及提高催化和气体敏感系数起很大作用.

Abstract: Nanosized γ-Fe2O3 and γ-Fe2O3/SiO2 complex oxides were prepared by the sol-gel method, and sensing elements were fabricated. Phase composition, grain size, part
icle size distribution of the nanosized oxides were characterized by TG-DTA,X
RD,TEM and Zetasize distribution respectively. The sensitivity of the sensing el
ements to CO, H2, C2H4, C6H6 and the effects of calcination temperature on the sensitivity of two typical elements were examined. The operating temperature of elements to different gases was obtained. The results showed that phase transition temperature, thermal stability,catalytic activity and gas sensitivity of γ-Fe2 O3 were enhanced due to the SiO2 present. The thermal stability of gas sensing and catalytic materials based on γ-Fe2O3 was expected to be basically solved.