钴卟啉对空气氧化环己烯合成环己烯酮的催化作用
CIESC Journal
• 催化、动力学与反应器 • 上一篇 下一篇
刘文;刘强;郭灿城
湖南大学化学化工学院, 湖南 长沙 410082
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CATALYSIS OF SIMPLE COBALTPORPHYRIN FOR AERIAL OXIDATION OF CYCLOHEXENE TO CYCLOHEXENONE
LIU Wen;LIU Qiang;GUO Cancheng
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Abstract: Simple cobalt tetraphenylporphyrins was synthesized and used to catalyze cyclohexene oxidation into cyclohexenone with air in the absence of additives and solvents.The cobalt metalloporphyrin was found to be very effective catalysts for the synthesis of cyclohexenone from cyclohexene.The research results showed that the temperature, air velocity,catalyst concentration and pressure influenced the yield and conversion of cyclohexene oxidation with air.For cyclohexene oxidation catalyzed by simple cobalt tetraphenylporphyrin, the conversion of cyclohexene was up to 21%, the yield of cyclohexenone reached 75%, under the optimum conditions of 0.4 MPa, 80 ℃ and 2.3×10-5mol8226;L-1 cobalt tetraphenylporphyrin.
刘文;刘强;郭灿城.
LIU Wen;LIU Qiang;GUO Cancheng.
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https://hgxb.cip.com.cn/CN/Y2004/V55/I9/1537