• THERMODYNAMICS AND CHEMICAL…… • 上一篇 下一篇
马庆兰a; 陈光进a; 郭天民a; 张坤b; Julian Y. Zuoc; Dan Zhangc; Heng-Joo Ngc
MA Qinglana; CHEN Guangjina; GUO Tianmina; ZHANG Kunb; Julian Y. Zuoc; Dan Zhangc; Heng-Joo Ngc
摘要: In this work, a thermodynamic model is developed for prediction of structure H hydrate formation. The model combines the Peng-Robinson equation of state for the vapor, liquid and aqueous phases with the extended Ng-Robinson hydrate model for gas hydrate formation of all three structures. The parameters of 14 structure-H hydrate formers are determined based on the experimental data of structure-H hydrates in the literature. The expression of fugacity of water in the empty hydrate phase is correlated for calculating structure-H hydrate formation conditions in the absence of free water. The model is tested by predicting hydrate formation conditions of a number of structure-H hydrate forming systems which are in good agreement with the experimental data. The proposed model is also applied to the prediction of hydrate formation conditions for various reservoir fluids such as natural gas and gas condensate.