环戊二烯加氢宏观动力学的研究

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环戊二烯加氢宏观动力学的研究

郭世卓^a,b;徐泽辉^a;夏蓉晖^a;周飞^a;房鼎业^b

^a Shanghai Petrochemical Company Ltd., Shanghai 200540, China
^b College of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2005-10-28 发布日期:2005-10-28
通讯作者: 郭世卓

Kinetics on Hydrogenation of Cyclopentadiene over Pd/γ-Al₂O₃ Catalyst

GUOShizhuo^a,b;XUZehui^a;XIARonghui^a;ZHOUFei^a; FANGDingye^b

^a Shanghai Petrochemical Company Ltd., Shanghai 200540, China
^b College of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

Received:1900-01-01 Revised:1900-01-01 Online:2005-10-28 Published:2005-10-28
Contact: GUO Shizhuo

摘要/Abstract

摘要： The macrokinetics of hydrogenation of cyclopentadiene was investigated over Pdγ-Al2O3 catalyst. Experimental results showed that the relationship between the constituents and reaction time was in agreement with the characteristic of consecutive irreversible first-order reaction. Analysis on the reaction mechanism of selective hydrogenation of cyclopentadiene indicated that it is reasonable to express the hydrogenation rate of cyclopentadiene in the power law form. Parameters of the kinetic model were obtained by the Gauss-Newton method based on the experimental data. From the statistic test and residual error distribution the kinetic model was proved to be adequate.

关键词: 环戊二烯;环戊烯;加氢反应;宏观动力学;Pd/γ-Al2O3催化剂

Abstract: The macrokinetics of hydrogenation of cyclopentadiene was investigated over Pdγ-Al2O3 catalyst. Experimental results showed that the relationship between the constituents and reaction time was in agreement with the characteristic of consecutive irreversible first-order reaction. Analysis on the reaction mechanism of selective hydrogenation of cyclopentadiene indicated that it is reasonable to express the hydrogenation rate of cyclopentadiene in the power law form. Parameters of the kinetic model were obtained by the Gauss-Newton method based on the experimental data. From the statistic test and residual error distribution the kinetic model was proved to be adequate.

Key words: cyclopentadiene, cyclopentene, kinetic, mechanism, hydrogenation

郭世卓,徐泽辉,夏蓉晖,周飞,房鼎业. 环戊二烯加氢宏观动力学的研究[J]. CIESC Journal.

GUOShizhuo,XUZehui,XIARonghui,ZHOUFei, FANGDingye. Kinetics on Hydrogenation of Cyclopentadiene over Pd/γ-Al₂O₃ Catalyst[J]. .

环戊二烯加氢宏观动力学的研究

Kinetics on Hydrogenation of Cyclopentadiene over Pd/γ-Al₂O₃ Catalyst

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环戊二烯加氢宏观动力学的研究

Kinetics on Hydrogenation of Cyclopentadiene over Pd/γ-Al2O3 Catalyst

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Kinetics on Hydrogenation of Cyclopentadiene over Pd/γ-Al₂O₃ Catalyst