CIESC Journal

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吸氧多层薄膜内脱氧树脂层的传质与反应模型

王车礼;承民群;袭兆蓉   

  1. 江苏工业学院精细石油化工省重点实验室,江苏 常州 213016

  • 出版日期:2005-05-25 发布日期:2005-05-25

Diffusion and reaction model in deoxidizing resin layers of oxygen absorbing multi-layer films

WANG Cheli;CHENG Minlian;QIU Zhaorong

  

  • Online:2005-05-25 Published:2005-05-25

摘要: 制备了多种配方的脱氧树脂薄膜,测定了铁粉含量、铁粉粒度、卤化物、偶联剂、填充剂及调湿时间等因素对脱氧树脂薄膜吸氧性能的影响,建立了脱氧树脂薄膜吸氧过程的传质与反应模型.该模型表明,当M1/2>3时,吸氧过程为快速反应,吸氧速率与膜厚无关.当M1/2<0.3时,吸氧过程为慢速反应,吸氧速率与De无关,膜内氧气浓度均匀,且等于气固界面浓度.采用多种配方脱氧树脂薄膜的吸氧实验表明,该模型与实验结果吻合良好.

Abstract: A variety of deoxidizing resin films were prepared, which were key layers of the oxygen absorbing multi-layer films.The effects of iron content, iron particle size, metal halide content, coupling agent, inorganic filler, and moisture regulating time on oxygen-absorbing rate were investigated.A model of oxygen-absorbing rate in deoxidizing resin films was developed based on the quasi-steady state assumption. According to the model, if M1/2>3, the process was a rapid reaction,and the film thickness had no effect on oxygen-absorbing rate.But when M1/2<0.3,the process was a slow reaction, the diffusion coefficient De showed no effect on oxygen-absorbing rate, and the oxygen concentration in the film was uniform and equal to that at gas-solid interface.The experimental results of oxygen-absorbing rate in deoxidizing resin films agreed well with the model proposed.