Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen

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Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen

JIHongbing(纪红兵),HUANGYueying(黄月英),QIANYu(钱宇),WANGTingting(王婷婷)andZHANGMeiying(张美英)

School of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640, China
Analytical and Testing Center, South China University of Technology, Guangzhou 510640, China

收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2006-02-28 发布日期:2006-02-28
通讯作者: QIAN Yu(钱宇)

Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen

Received:1900-01-01 Revised:1900-01-01 Online:2006-02-28 Published:2006-02-28

摘要/Abstract

摘要： An efficient reduction system of benzaldehyde with hydrogen under ambient pressure was developed using facile NiO catalyst. The non-aromatic solvents such as cyclohexane, tetrahydrofuran (THF) and n-hexane, and the addi-tive with strong basicity e.g. KOH, were necessary for smooth conversion of the substrate. That the catalyst can be recov-ered and reused for nine times without loss of catalytic activity indicates that this catalyst is a recyclable one for benzal-dehyde reduction.

关键词: reduction;nickel oxide;benzaldehyde;recyclable catalyst

Key words: reduction, nickel oxide, benzaldehyde, recyclable catalyst

JIHongbing(纪红兵),HUANGYueying(黄月英),QIANYu(钱宇),WANGTingting(王婷婷)andZHANGMeiying(张美英). Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen[J]. CIESC Journal.

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Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen

Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen

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