6.0mol•L－1KOH溶液中锌单晶（002）和（100）晶面的电化学行为

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6.0mol•L－1KOH溶液中锌单晶（002）和（100）晶面的电化学行为

王华清^a; 周上祺^b; 陈昌国^c; 王秋虹^a

^a Department of Power Engineering, Chongqing Communication College, Chongqing 400035, China
^b College of Material Science and Engineering, Chongqing University, Chongqing 400044,China
^c College of Chemical Engineering, Chongqing University, Chongqing 400044,China

收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2006-08-28 发布日期:2006-08-28
通讯作者: 王华清

Electrochemical Performance of Zn(002) and Zn(100) Single Crystals in 6.0mol•L－1 KOH

WANGHuaqing^a; ZHOUShangqi^b; CHENChangguo^c; WANGQiuhong^a

^a Department of Power Engineering, Chongqing Communication College, Chongqing 400035, China
^b College of Material Science and Engineering, Chongqing University, Chongqing 400044,China
^c College of Chemical Engineering, Chongqing University, Chongqing 400044,China

Received:1900-01-01 Revised:1900-01-01 Online:2006-08-28 Published:2006-08-28
Contact: WANG Huaqing

摘要/Abstract

摘要： In this article, the electrochemical performance of the electrodes of zinc polycrystal, Zn(002) and Zn(100) single crystals were studied by the Tafel line extrapolation of the potentio-dynamic polarization curves, the cyclic voltammetry and the charge/discharge experiment. The results shows that in 6.0 mol•L－1 KOH solution the corrosion rate of Zn polycrystal, Zn(100) and Zn(002) single crystals decreases in turn; and the reversibility and the charge/discharge performance of Zn single crystal was superior to Zn polycrystal. The dendrite growth of the sur-face of Zn polycrystal was easier than Zn single crystal during the stages of charge/discharge.

关键词: zinc single crystal electrode;alkaline solution;corrosion;cyclic voltammetry;dendrite

Abstract: In this article, the electrochemical performance of the electrodes of zinc polycrystal, Zn(002) and Zn(100) single crystals were studied by the Tafel line extrapolation of the potentio-dynamic polarization curves, the cyclic voltammetry and the charge/discharge experiment. The results shows that in 6.0 mol•L－1 KOH solution the corrosion rate of Zn polycrystal, Zn(100) and Zn(002) single crystals decreases in turn; and the reversibility and the charge/discharge performance of Zn single crystal was superior to Zn polycrystal. The dendrite growth of the sur-face of Zn polycrystal was easier than Zn single crystal during the stages of charge/discharge.

Key words: zinc single crystal electrode, alkaline solution, corrosion, cyclic voltammetry, dendrite

王华清, 周上祺, 陈昌国, 王秋虹. 6.0mol•L－1KOH溶液中锌单晶（002）和（100）晶面的电化学行为[J]. CIESC Journal.

WANGHuaqing, ZHOUShangqi, CHENChangguo, WANGQiuhong. Electrochemical Performance of Zn(002) and Zn(100) Single Crystals in 6.0mol•L－1 KOH[J]. .

参考文献

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6.0mol•L－1KOH溶液中锌单晶（002）和（100）晶面的电化学行为

Electrochemical Performance of Zn(002) and Zn(100) Single Crystals in 6.0mol•L－1 KOH

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