Abstract: Several analytical methods to dertermine rhodium such as gravimetric method, inductively coupled plasma spectrometry (ICP), flame atomic absorption spectrometry (FAAS) and FAAS improved (FAASI) by a calibration constant K were studied in this paper. The results showed that for pure rhodium plating solution, gravimetric method was an accurate method to determine rhodium with relative deviation less than 4%, and especially, the deviation was only within 0.2% with alkaline sodium borohydride as reducing agent. For highly contaminated rhodium solution, ICP and FAASI were very good choice and the relative deviation was less than 1%.