CIESC Journal

• 材料科学与工程 • 上一篇    下一篇

丙烯酸系高吸水树脂的紫外线分解动力学行为

崔英德;黎新明;贾振宇;尹国强;廖列文;梁世强   

  1. 仲恺农业技术学院绿色化工研究所,广东 广州 510225

  • 出版日期:2006-11-25 发布日期:2006-11-25

Decomposition kinetics of acrylic acid-based super-absorbent resin by ultraviolet

CUI Yingde;LI Xinming;JIA Zhenyu;YIN Guoqiang;LIAO Liewen;LIANG Shiqiang   

  • Online:2006-11-25 Published:2006-11-25

摘要: 建立了丙烯酸系高吸水树脂耐候性的评价体系和研究方法,采用紫外线辐照法研究了N,N′-亚甲基双丙烯酰胺交联的丙烯酸/丙烯酰胺共聚物高吸水树脂的分解动力学行为.结果表明:丙烯酸系高吸水树脂的老化机理在于交联剂N,N′-亚甲基双丙烯酰胺在紫外线的作用下水解,导致树脂的交联结构解体.紫外线强度较低时,其分解速度受光反应控制;紫外线强度较高时,则受热反应控制.丙烯酰胺用量增加到70%(质量)、交联剂用量增加到0.139%(质量)、丙烯酸中和度增加到100%,树脂在相同条件下的失重率分别从100%、100%以及42.0%降低到0、9.3%和30.4%.

Abstract: The research method and evaluation system of the weather resistance of super-absorbent resin based on acrylic acid were established,and the decomposition kinetics of such a super-absorbent resin were studied with ultra-violet irradiation.The results showed that the aging mechanism of such a super-absorbent resin was the hydrolysis of crosslinker N,N′-methylenebisacrylamide hydrolyzed under ultra-violet light,leading to disassembly of the crosslinked structure.The decomposition rate was controlled by light reaction when the intensity of ultra-violet light was low but was controlled by hot reaction when the intensity of ultra-violet light was high.When the dosage of acrylamide increased to 70%,the dosage of NN′-methylenebisacrylamide increased to 0.139%,and the neutralization degree of acrylic acid increased to 100%,the loss of mass decreased from 100%,100% and 42.0% to 0、9.3% and 30.4%,respectively.