CIESC Journal

• 能源和环境工程 • 上一篇    下一篇

含油污泥回转式连续热解——质能平衡及产物分析

陈超;李水清;岳长涛;Kruttschnitt T;Pruckner E;姚强   

  1. 清华大学热科学与动力工程教育部重点实验室,北京 100084;德国斯坦拜恩过程、能源和环境技术转让中心;中国石油大学(北京) 化工学院 ,北京 102249

  • 出版日期:2006-03-25 发布日期:2006-03-25

Lab-scale pyrolysis of oil sludge in continuous rotating reactor:mass/energy balance and product analysis

CHEN Chao;LI Shuiqing;YUE Changtao;Kruttschnitt T;Pruckner E;YAO Qiang   

  • Online:2006-03-25 Published:2006-03-25

摘要: 含油污泥是石油开采和石油化工行业中最常见的工业固体废物,而热解技术由于具有能量或物质回收效率高,环境污染小的特点,也已成为继焚烧技术之后又一重要的固体废物处理技术.在一台处理量为1~2 kg•h-1的回转式连续反应器上进行了含油污泥热解的实验研究,以氩气为反应气氛,热解温度为550℃,并对气、液、固三相产物进行了详细的分析.结果表明:实验的质量和能量平衡误差分别在10%和15%以内,有效地回收了含油污泥中的挥发性有机物VOCs和半挥发性有机物SVOCs,气液固产物的质量比分别为10%、20%和70%,其中热解气体(含载气)的热值为11 MJ•m-3,主要成分为甲烷、二氧化碳、乙烷和氢气等;同时测定了热解油的物化性质、馏分和元素组成,并结合GC-MS分析了主要芳香烃的分布,分析所得热解油以柴油馏分(75%)为主,热值可达43 MJ•kg-1左右,可直接作燃料油使用,但其杂原子和芳香烃含量较高,油品质量与成品油还有一定差距;此外对热解固体残渣的分析显示,残渣以沙粒为主,含碳量在4%~6%之间,且固定了大多数金属元素(Pb、Cr、Ni除外),可用于铺路或建材.

Abstract: Oil sludge is one of the major industrial solid wastes from petroleum production and refining.Pyrolysis of oil sludge is one of most promising alternative to remove the VOCs (volatile organic compounds) and SVOCs (semivolatile organic compounds) from the solid waste and recover the energy in the gaseous and liquid products, with the minimum pollution to the environment.In this paper, oil sludge was pyrolyzed in a 1—2 kg•h-1 continuous tubular reactor with internal rotating paddles, which can be regarded as a simplified model of commercial rotary kiln pyrolyzer.The experiments were conducted at 550℃ in argon atmosphere, and mass balance and energy balance were obtained with error no more than 10% and 15%, respectively.About 70%(mass) of solid residue, 20%(mass) of condensate, and 10%(mass) of non-condensable gas were produced.Methane, carbon dioxide, ethane and hydrogen were the major components in the low-calorific gas product (carrier gas Ar included)with calorific value around 11 MJ•m-3.Physico-chemical properties, distillation fractions, elemental contents, hydrocarbon composition were analyzed for the product oil.Diesel fraction was up to 75% and the calorific value was about 43 MJ•kg-1 and it could be used as fuel oil directly.However, due to the high contents of S, N, O and PAH, the quality of the fraction was not up to diesel specification.The majority of metal elements were fixed in the pyrolytic residues, while Pb, Cr and Ni were found to be enriched in the fly ash from hot filter.The solid residues contained much sand and inorganic ash.It could be reused as construction material.