[bupy]BF4-AlCl3离子液体上甲苯和间戊二烯的烷基化反应

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[bupy]BF₄-AlCl₃离子液体上甲苯和间戊二烯的烷基化反应

田力¹; 曹发海¹; 房鼎业¹; 郭世卓²

¹ Research Institute of Chemical Technology, East China University of Science and Technology, Shanghai 200237, China
² Chemical Research Institute, Shanghai Petrochemical Company Limited, SINOPEC, Shanghai 200540, China

收稿日期:2006-11-28 修回日期:1900-01-01 出版日期:2007-10-28 发布日期:2007-10-28
通讯作者: 田力

Alkylation of toluene with 1,3-pentadiene over [bupy]BF₄-AlCl₃ ionic liquid catalyst

TIAN Li¹; CAO Fahai¹; FANG Dingye¹; GUO Shizhuo²

¹ Research Institute of Chemical Technology, East China University of Science and Technology, Shanghai 200237, China
² Chemical Research Institute, Shanghai Petrochemical Company Limited, SINOPEC, Shanghai 200540, China

Received:2006-11-28 Revised:1900-01-01 Online:2007-10-28 Published:2007-10-28
Contact: TIAN Li

摘要/Abstract

摘要： The alkylation of toluene with 1,3-pentadiene to produce pentyltoluene was carried out to obtain 2,6-dimethylnaphalene, which is an important intermediate during the production of 2,6-naphthalene dicarboxylic acid. Based on our previous work using anhydrous AlCl3 as catalyst, [bupy]BF4-AlCl3 ionic liquids were employed to catalyze the reaction of 1,3-pentadiene with toluene. The experimental results show that [bupy]BF4-AlCl3 ionic liquids are suitable for the reaction especially when the molar ratio of AlCl3 to [bupy]BF4 is 1.75︰1, and the reaction could proceed at the temperature as low as 0℃. It could be as active as pure AlCl3, but much more environmentally friendly.

关键词: [bupy]BF₄-AlCl₃ ionic liquids;toluene;1;3-pentadiene;pentenyltoluene

Abstract: The alkylation of toluene with 1,3-pentadiene to produce pentyltoluene was carried out to obtain 2,6-dimethylnaphalene, which is an important intermediate during the production of 2,6-naphthalene dicarboxylic acid. Based on our previous work using anhydrous AlCl3 as catalyst, [bupy]BF4-AlCl3 ionic liquids were employed to catalyze the reaction of 1,3-pentadiene with toluene. The experimental results show that [bupy]BF4-AlCl3 ionic liquids are suitable for the reaction especially when the molar ratio of AlCl3 to [bupy]BF4 is 1.75︰1, and the reaction could proceed at the temperature as low as 0℃. It could be as active as pure AlCl3, but much more environmentally friendly.

Key words: [bupy]BF4-AlCl3 ionic liquids, toluene, 1, 3-pentadiene, pentenyltoluene

田力, 曹发海, 房鼎业, 郭世卓. [bupy]BF₄-AlCl₃离子液体上甲苯和间戊二烯的烷基化反应[J]. CIESC Journal.

TIAN Li, CAO Fahai, FANG Dingye, GUO Shizhuo. Alkylation of toluene with 1,3-pentadiene over [bupy]BF₄-AlCl₃ ionic liquid catalyst[J]. .

参考文献

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[bupy]BF₄-AlCl₃离子液体上甲苯和间戊二烯的烷基化反应

Alkylation of toluene with 1,3-pentadiene over [bupy]BF₄-AlCl₃ ionic liquid catalyst

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