全氟壬烯氟两相体系及其在酯化反应中的应用

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全氟壬烯氟两相体系及其在酯化反应中的应用

史鸿鑫; 项菊萍; 武宏科

State Key Laboratory Breeding Base of Green Chemistry Synthesis-Technology, Zhejiang University of Technology, Hangzhou 310032, China

收稿日期:2006-11-28 修回日期:1900-01-01 出版日期:2007-12-28 发布日期:2007-12-28
通讯作者: 史鸿鑫

Fluorous biphase system of C₉F₁₈ and its use in esterification

SHI Hongxin; XIANG Juping; WU Hongke

State Key Laboratory Breeding Base of Green Chemistry Synthesis-Technology, Zhejiang University of Technology, Hangzhou 310032, China

Received:2006-11-28 Revised:1900-01-01 Online:2007-12-28 Published:2007-12-28
Contact: SHI Hongxin

摘要/Abstract

摘要： Some apolar organic solvents is miscible with perfluorous nonene to form fluorous biphase systems. Perfluorous nonene could be used as a green solvent in equimolar esterification of carboxylic acids with alcohols without removal of water or ester formed. Perfluorous nonene made the esterification equilibrium to move right and the yields of esterification to enhance in different degrees as compared with that in the absence of perfluorous nonene. After esterification perfluorous nonene is easy to be recovered and recycled.

关键词: perfluorous nonene;fluorous biphase system;esterification;green solvent

Abstract: Some apolar organic solvents is miscible with perfluorous nonene to form fluorous biphase systems. Perfluorous nonene could be used as a green solvent in equimolar esterification of carboxylic acids with alcohols without removal of water or ester formed. Perfluorous nonene made the esterification equilibrium to move right and the yields of esterification to enhance in different degrees as compared with that in the absence of perfluorous nonene. After esterification perfluorous nonene is easy to be recovered and recycled.

Key words: perfluorous nonene, fluorous biphase system, esterification, green solvent

史鸿鑫, 项菊萍, 武宏科. 全氟壬烯氟两相体系及其在酯化反应中的应用[J]. CIESC Journal.

SHI Hongxin, XIANG Juping, WU Hongke. Fluorous biphase system of C₉F₁₈ and its use in esterification[J]. .

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全氟壬烯氟两相体系及其在酯化反应中的应用

Fluorous biphase system of C₉F₁₈ and its use in esterification

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Fluorous biphase system of C9F18 and its use in esterification

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Fluorous biphase system of C₉F₁₈ and its use in esterification