化工学报 ›› 2007, Vol. 58 ›› Issue (11): 2911-2914.

• 能源和环境工程 • 上一篇    下一篇

镀铬化工废水对发光菌的综合毒性

董玉瑛;雷炳莉;张阳;鲍雅静   

  1. 大连民族学院环境工程系;中国科学院生态环境研究中心环境水化学实验室
  • 出版日期:2007-11-05 发布日期:2007-11-05

Comprehensive toxicity analysis of chromeplating effluents to Photobacterium phosphoreum

DONG Yuying; LEI Bingli;ZHANG Yang;BAO Yajing   

  • Online:2007-11-05 Published:2007-11-05

摘要: 通过测定pH值、电导率和COD等主要理化性质,对3种不同工艺段的电镀废水进行了表征。应用发光细菌法测定了废水的生物毒性,并根据水质毒性分级标准进行了评价。结果表明,电镀废水的EC50值与COD和电导率值虽然存在一定的相关性,但仅凭化学方法对理化指标进行监测不能定量反映废水对生物造成的危害,必需将它与生物分析方法相结合。综合评价废水的毒性和理化指标,有益于制定出可靠的废水排放标准。同时结合电导率和化学需氧量(COD)值初步分析了3种电镀废水对发光菌造成毒性的毒物类型,这为进一步研究引起电镀废水毒性的因子鉴别奠定基础。

关键词:

镀铬废水, 发光菌, 毒性分析, 毒性分级

Abstract:

Comprehensive evaluation of effluents is of great importance for environmental impact assessment.In this paper, three kinds of chromeplating effluents were characterized by determining pH, conductivity and COD values.The toxicity of these effluents to Photobacterium phosphoreum was also determined.According to the toxicity category standard, their order of toxicity intensity was obtained.Although there was a correlation between EC50, COD and conductivity to some extent, it was inappropriate to represent quantitatively the damages to organisms only by the physico-chemical properties of the chromeplating effluents.It was indicated that a combination of physico-chemical characterization and comprehensive toxicity analysis could provide the correct information for effluent discharge standards.In this study, causative toxic compound types in three kinds of electroplating effluents were also analyzed preliminarily according to conductivity, COD and EC50 values.It can provide the basis for toxicity identification evaluation of electroplating effluents.

Key words:

镀铬废水, 发光菌, 毒性分析, 毒性分级