CIESC Journal

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甲酸在钛基纳米多孔网状铂电极上的电化学氧化

易清风   

  1. 湖南科技大学化学化工学院
  • 出版日期:2007-02-05 发布日期:2007-02-05

Electrochemical oxidation of formic acid on novel titanium-supported nanoporous network platinum electrode

  • Online:2007-02-05 Published:2007-02-05

摘要: 将水热法和电解过程相结合,制备出一种新型的钛基纳米多孔网状铂电极(nanoPt),它具有特殊的网络状结构及巨大的表面积. 循环伏安曲线表明,在碱性溶液中,甲酸在nanoPt上的氧化电流密度远远大于在多晶Pt上的电流密度,其氧化峰电流几乎是后者的100倍;恒电位电解时,甲酸在nanoPt上的氧化电流开始时随时间的增加而增加,随后达到稳定,其稳定电流也明显高于多晶Pt;在nanoPt上甲酸的非线性现象出现的电流密度范围要比在多晶铂上的宽. 多次循环扫描和长时间电解实验表明. 这种钛基nanoPt结构稳定,催化剂颗粒不易脱落,有可能作为一种新型的燃料电池阳极材料而得到应用.

Abstract: A novel titanium-supported nanoporous network platinum electrode(nanoPt)with a enormous surface area was successfully fabricated with successive hydrothermal electrolytic processesIt was shown from cyclic voltammograms in alkaline solutions that current densities during the oxidation of formic acid on the nanoPt were much higher than those on a polycrystalline platinum(Pt),and that the oxidation peak current density on the nanoPt was almost 100 times higher than on PtIt was observed from chrono potentiometric measurements that steady-state current densities on the nanoPt were also much higher than on PtOscillatory behavior was observed both on Pt and on the nanoPt electrodes,but the linear galvanic voltammograms showed that oscillation arose in a much wider range of current densities on the nanoPt than on PtThis novel nanoporous platinum electrode could be used repeatedly and its electrocatalytic activity was stable significantlyIt would be a promising anodic material used in fuel cells.