化工学报 ›› 2008, Vol. 59 ›› Issue (2): 490-496.

• 材料化学工程与纳米技术 • 上一篇    下一篇

介孔TiO2晶须及其担载RuO2的电容性能

吕玲红,胡煜艳,朱育丹,吕志华,刘畅,冯新,陆小华   

  1. 南京工业大学化学化工学院,材料化学工程国家重点实验室
  • 出版日期:2008-02-05 发布日期:2008-02-05

Capacitance performance of mesoporous TiO2 whisker and composite loaded with RuO2

Lv Linghong, HU Yuyan, ZHU Yudan, Lv Zhihua, LIU Chang, FENG Xin, LU Xiaohua   

  • Online:2008-02-05 Published:2008-02-05

摘要:

烧结法制备的介孔TiO2晶须具有高结晶度,孔径可控,并且制备成本低,可以大规模生产。如能将该材料用于电化学电容器电极材料,则可以降低成本、提高电容器性能。采用孔径分布在10 nm左右的介孔TiO2晶须及其担载氧化钌的材料制备了电极,循环伏安法分析表明该材料在中性的0.1 mol·L-1的Na2SO4溶液中即具有典型的电容行为,并且在较宽的扫描范围表现出一定的电容特性;介孔TiO2晶须担载RuO2后,其电容性能优异,比电容达到940.4 F·g -1(以RuO2质量计),有可能作为电化学电容器的低成本大规模生产的电极材料。

关键词:

介孔TiO2晶须, RuO2;电容性能

Abstract:

Mesoporous TiO2 whisker prepared by sintering has high crystallinity, its pore size is controllable, and the cost is low, so it can be mass-produced.If the material is used in electrochemical capacitorelectrode, the cost of the capacitor will be cut down.In this paper, mesoporous TiO2 whisker with pore size around 10 nm and TiO2/RuO2 composite material were prepared to make electrodes.The results of cyclic voltammograms showed that the material had typical electrochemical capacitor property even in the neutral solution of 0.1 mol·L-1 Na2SO4.The capacitor property was within a wide scan range.When the mesoporous TiO 2 whisker was loaded with RuO 2, the performance was excellent, and its capacitance was up to 940.4 F·g-1 (divided by the mass of RuO 2), so it is feasible to use this material as mass-produced electrode material.

Key words:

介孔TiO2晶须, RuO2;电容性能