化工学报 ›› 2008, Vol. 59 ›› Issue (4): 1065-1069.

• 现代化工技术 • 上一篇    

氯碱厂多余次氯酸钠回收利用新型工艺设计

唐小红;刘福   

  1. 四川大学材料科学与工程学院,四川 成都 610065;四川教育学院物理系,四川 成都 610041;中国成达工程公司,四川 成都 610041
  • 出版日期:2008-04-05 发布日期:2008-04-05

New process design for reuse of redundant hypochlorite in chlor-alkali plants

TANG Xiaohong;LIU Fu   

  • Online:2008-04-05 Published:2008-04-05

摘要:

次氯酸钠(NaClO)是氯碱生产中作为氯气平衡的一个有效的副产品。在氯碱厂开停车时,常常产生次氯酸钠胀库现象,大量次氯酸钠溶液直排会造成严重的环境污染和物料浪费,影响工厂的正常生产。本文根据次氯酸钠在酸性条件下的分解特性,设计出循环利用次氯酸钠溶液反应流程装置,次氯酸钠溶液反应生成电解原料NaCl及用作销售的Cl2,使工厂不会因为次氯酸钠的胀库影响开车或停车,轻松应对开停车,既解决了次氯酸钠的排放问题,又保护了环境,而且还产生循环经济。一般情况下工厂在2~3.5年内就可收回投资成本。

关键词:

次氯酸钠, 氯气, 氯化钠

Abstract:

Sodium hypochlorite is an effective by-product in the chlor-alkali production in chlorine equilibrium and waste gas treatment.When start-up and shut-down are frequent in the chlor-alkali plant, a over bulged hypochlorite stock often appears.If the large quantity of hypochlorite is directly discharged, it will cause heavy pollution and material waste, and it will affect the normal plant running when the bulged hypochlorite stock gets worse.Based on the decomposition of hypochlorite under acidic condition, a reaction unit was designed in recycle use of the hypochlorite solution to produce NaCl useful for electrolysis and chlorine gas for market sale.In this way the over bulged hypochlorite stock problem could be solved.Not only there is no hypochlorite discharged, but also the environment could be protected and economic benefit could be achieved by recycle use of hypochlorite.The investment will be recovered in 2—3.5 years.

Key words:

次氯酸钠, 氯气, 氯化钠