Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol

CIESC Journal ›› 2009, Vol. 17 ›› Issue (3): 401-406.

Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol

梁英华¹, 郭红霞^1,2, 陈红萍¹, 吕敬德³, 张波波¹

1. School of Chemical Engineering and Biological Technology, Hebei Polytechnic University, Tangshan 063009, China;
2. College of Light Industry, Hebei Polytechnic University, Tangshan 063000, China;
3. Tangshan Zhongrun Coal Chemical Co., Ltd., Tangshan 063611, China

收稿日期:2008-10-17 修回日期:2008-12-05 出版日期:2009-06-28 发布日期:2009-06-28
通讯作者: LIANG Yinghua,E-mail:Liangyh64@yahoo.com.cn

Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol

LIANG Yinghua¹, GUO Hongxia^1,2, CHEN Hongping¹, LÜJingde³, ZHANG Bobo¹

1. School of Chemical Engineering and Biological Technology, Hebei Polytechnic University, Tangshan 063009, China;
2. College of Light Industry, Hebei Polytechnic University, Tangshan 063000, China;
3. Tangshan Zhongrun Coal Chemical Co., Ltd., Tangshan 063611, China

Received:2008-10-17 Revised:2008-12-05 Online:2009-06-28 Published:2009-06-28

摘要/Abstract

摘要： Effect of doping cerium in the support on the catalytic activity and side product of the reaction in the oxidative carbonylation of phenol to diphenyl carbonate (DPC) over the catalyst Pd-Co/Cu-Co-Mn mixed oxides was studied. The specific surface areas, crystal phase, valency, and content of the element on the surface of the catalysts were determined, and the products were detected by gas chromatograph/mass spectrometry (GC-MS). It is found that the catalyst without Ce shows higher activity than that with Ce, and the yields of DPC for the two catalysts can reach 30% and 23%, respectively. However, doping cerium can prevent the formation of 2-hydroxyphenyl benzoate and p-bromophenyl phenyl carbonate.

关键词: diphenyl carbonate, oxidative carbonylation, doping cerium, sol-gel method

Abstract: Effect of doping cerium in the support on the catalytic activity and side product of the reaction in the oxidative carbonylation of phenol to diphenyl carbonate (DPC) over the catalyst Pd-Co/Cu-Co-Mn mixed oxides was studied. The specific surface areas, crystal phase, valency, and content of the element on the surface of the catalysts were determined, and the products were detected by gas chromatograph/mass spectrometry (GC-MS). It is found that the catalyst without Ce shows higher activity than that with Ce, and the yields of DPC for the two catalysts can reach 30% and 23%, respectively. However, doping cerium can prevent the formation of 2-hydroxyphenyl benzoate and p-bromophenyl phenyl carbonate.

Key words: diphenyl carbonate, oxidative carbonylation, doping cerium, sol-gel method

梁英华, 郭红霞, 陈红萍, 吕敬德, 张波波. Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol[J]. CIESC Journal, 2009, 17(3): 401-406.

LIANG Yinghua, GUO Hongxia, CHEN Hongping, LÜJingde, ZHANG Bobo. Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol[J]. , 2009, 17(3): 401-406.

参考文献

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Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol

Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol

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