CIESC Journal ›› 2009, Vol. 17 ›› Issue (4): 661-666.

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Effects of Temperature on the Preparation of Magnesium Carbonate Hydrates by Reaction of MgCl2 with Na2CO3

程文婷1, 李志宝1, George P. Demopoulos2   

  1. 1. Key Laboratory of Green Process and Engineering, Institute of Process Engineering, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Chinese Academy of Sciences, Beijing 100190, China;
    2. Department of Mining, Materials Engineering, McGill University, 3610 University Street, Montreal, Quebec, Canada
  • 收稿日期:2008-11-28 修回日期:2009-02-28 出版日期:2009-08-28 发布日期:2010-12-30
  • 通讯作者: LI Zhibao, E-mail: zhibaoli@home.ipe.ac.cn
  • 作者简介:
  • 基金资助:
    Supported by the National Natural Science Foundation of China(20876161);the National Basic Research Program of China(2007CB613501,2009CB219904)

Effects of Temperature on the Preparation of Magnesium Carbonate Hydrates by Reaction of MgCl2 with Na2CO3

CHENG Wenting1, LI Zhibao11, George P. Demopoulos2   

  1. 1. Key Laboratory of Green Process and Engineering, Institute of Process Engineering, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Chinese Academy of Sciences, Beijing 100190, China;
    2. Department of Mining, Materials Engineering, McGill University, 3610 University Street, Montreal, Quebec, Canada
  • Received:2008-11-28 Revised:2009-02-28 Online:2009-08-28 Published:2010-12-30
  • Supported by:
    Supported by the National Natural Science Foundation of China(20876161);the National Basic Research Program of China(2007CB613501,2009CB219904)

摘要: Homogeneous(unseeded)precipitation of magnesium carbonate hydrates by the reaction of MgCl2 with Na2CO3 in supersaturated solutions between 273 and 363K was investigated.The compositions,morphologies and filtration characteristics of the precipitates were studied in detail.The magnesium carbonate hydrates obtained at 313K and in the range of 343-363K showed good morphologies and filtration characteristics.Magnesium oxides(MgO)with high purity(97.6%-99.4%)were obtained by calcining magnesium carbonate hydrates at 1073K.

关键词: homogeneous precipitation, magnesium carbonate hydrates, magnesium oxide, filtration characteristic

Abstract: Homogeneous(unseeded)precipitation of magnesium carbonate hydrates by the reaction of MgCl2 with Na2CO3 in supersaturated solutions between 273 and 363K was investigated.The compositions,morphologies and filtration characteristics of the precipitates were studied in detail.The magnesium carbonate hydrates obtained at 313K and in the range of 343-363K showed good morphologies and filtration characteristics.Magnesium oxides(MgO)with high purity(97.6%-99.4%)were obtained by calcining magnesium carbonate hydrates at 1073K.

Key words: homogeneous precipitation, magnesium carbonate hydrates, magnesium oxide, filtration characteristic