Preparation of Organic/Inorganic Hybrid Polymer Emulsions with High Silicon Content and Sol-gel-derived Thin Films

CIESC Journal ›› 2010, Vol. 18 ›› Issue (1): 156-163.

Preparation of Organic/Inorganic Hybrid Polymer Emulsions with High Silicon Content and Sol-gel-derived Thin Films

廖文波, 瞿金清, 李忠, 陈焕钦

School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China

收稿日期:2009-06-03 修回日期:2009-08-09 出版日期:2010-02-28 发布日期:2010-12-30
通讯作者: QU Jinqing,E-mail: cejqqu@scut.edu.cn
作者简介:
基金资助:
Supported by the Program for New Century Excellent Talents in University(NCET-08-0204);National Natural Science Foundation of China(20976060);the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Edu-cation Ministry (China)

Preparation of Organic/Inorganic Hybrid Polymer Emulsions with High Silicon Content and Sol-gel-derived Thin Films

LIAO Wenbo, QU Jinqing, LI Zhong, CHEN Huanqin

School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China

Received:2009-06-03 Revised:2009-08-09 Online:2010-02-28 Published:2010-12-30
Supported by:
Supported by the Program for New Century Excellent Talents in University(NCET-08-0204);National Natural Science Foundation of China(20976060);the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Edu-cation Ministry (China)

摘要/Abstract

摘要： A novel polymer/SiO₂ hybrid emulsion(PAES) was prepared by directly mixing colloidal silica with polyacrylate emulsion(PAE)modified by a saline coupling agent.The sol-gel-derived thin films were obtained by addition of co-solvents into the PAES.The effects of γ-methacryloxypropy ltrimethoxysilane(KH-570) content and co-solvent on the properties of PAES films were investigated.Dynamic laser scattering(DLS) data indicate that the average diameter of PAES(96 nm) is slightly larger than that of PAE(89 nm).Transmission electron microscopy (TEM) photo discloses that colloidal silica particles are dispersed uniformly around polyacrylate particles and some of the colloidal silica particles are adsorbed on the surface of PAE particles.The crosslinking degree data and Fourier transform infrared(FT-IR)spectra confirm that the chemical structure of the PAES is changed to form Si-O-Si-polymer crosslinking networks during the film formation.Atomic force microscope(AFM) photos show the solvent induced sol-gel process of colloidal silica and the Si-based polymer distribution on the film surface of the dried PAES.Thermogravimetric analysis(TGA) curves demonstrate that the PAES films display much better thermal stability than PAE.

关键词: colloidal silica, polymer/SiO₂ hybrid emulsions, sol-gel process, water resistance

Abstract: A novel polymer/SiO₂ hybrid emulsion(PAES) was prepared by directly mixing colloidal silica with polyacrylate emulsion(PAE)modified by a saline coupling agent.The sol-gel-derived thin films were obtained by addition of co-solvents into the PAES.The effects of γ-methacryloxypropy ltrimethoxysilane(KH-570) content and co-solvent on the properties of PAES films were investigated.Dynamic laser scattering(DLS) data indicate that the average diameter of PAES(96 nm) is slightly larger than that of PAE(89 nm).Transmission electron microscopy (TEM) photo discloses that colloidal silica particles are dispersed uniformly around polyacrylate particles and some of the colloidal silica particles are adsorbed on the surface of PAE particles.The crosslinking degree data and Fourier transform infrared(FT-IR)spectra confirm that the chemical structure of the PAES is changed to form Si-O-Si-polymer crosslinking networks during the film formation.Atomic force microscope(AFM) photos show the solvent induced sol-gel process of colloidal silica and the Si-based polymer distribution on the film surface of the dried PAES.Thermogravimetric analysis(TGA) curves demonstrate that the PAES films display much better thermal stability than PAE.

Key words: colloidal silica, polymer/SiO₂ hybrid emulsions, sol-gel process, water resistance

廖文波, 瞿金清, 李忠, 陈焕钦. Preparation of Organic/Inorganic Hybrid Polymer Emulsions with High Silicon Content and Sol-gel-derived Thin Films[J]. CIESC Journal, 2010, 18(1): 156-163.

LIAO Wenbo, QU Jinqing, LI Zhong, CHEN Huanqin. Preparation of Organic/Inorganic Hybrid Polymer Emulsions with High Silicon Content and Sol-gel-derived Thin Films[J]. , 2010, 18(1): 156-163.

参考文献

1 Zou, M.X., Zhao, Q.C., Nie, J., Zhang, Z.C., “Preparation and characterization of polysiloxane polyacrylates composite lattices by two seeded emulsion polymerization and their film properties”, J. Appl. Poly. Sci., 103, 1406-1411 (2007).
2 Zou, M.X., Huang, F.Z., Nie, J., Zhang, Z.C., Ge, X.W., “Preparation and characterization of polysiloxane-polyacrylate composite lattices and their film properties”, Polym. Int., 54, 861-869 (2005).
3 Tamai, T., Watanabe, M., “Acrylic polymer/silica hybrids prepared by emulsifier-free emulsion polymerization and sol-gel process”, J. Poly. Sci., Part A: Polym Chem., 44, 273-280 (2006).
4 Watanabe, M., Tamai, T., “Acrylic polymer/silica organic-inorganic hybrid emulsions for coating materials: Role of the silane coupling agent”, J. Poly. Sci., Part A: Polym. Chem., 44, 4736-4742 (2006).
5 Patel, S., Bandyopadhyay, A., Vijayabaskar, V., Bhowmick, A.K., “Effect of microstructure of acrylic copolymer/terpolymer on the properties of silica based nanocomposites prepared by sol-gel technique”, Polymer, 46, 8079-8090 (2005).
6 Huang, S.L., Chin, W.K., Yang, W.P., “Structural characteristics and properties of silica/poly(2-hydroxyethyl methacrylate) (PHEMA) nanocomposites prepared by mixing colloidal silica or tetraethyloxysilane (TEOS) with PHEMA”, Polymer, 46, 1865-1877 (2005).
7 Ma, J.Z., Hu, J., Zhang, Z.J., “Polyacrylate/silica nanocomposite materials prepared by sol-gel process”, Eur. Polym. J., 43, 4169-4177 (2007).
8 Yu, Y.Y., Chen, C.Y., Chen, W.C., “Synthesis and characterization of organic-inorganic hybrid thin films from poly(acrylic) and monodispersed colloidal silica”, Polymer, 44, 593-601 (2003). 9 Yu, Y.Y., Chen, W.C., “Transparent organic-inorganic hybrid thin films prepared from acrylic polymer and aqueous monodispersed colloi
dal silica”, Mate. Chem. Phys., 82, 388-395 (2003).
10 Hern ndez, J.C., Pradas, M.M., Ribelles, J.L., “Properties of poly(2-heydroxyethyyl acrylate)-silica nanocomposite obtained by sol-gel process”, J. Non-Crys. Soli., 354, 1900-1908 (2008).
11 Zou, H., Wu, S.S., Shen, J., “Polymer/silica nanocomposites: preparation, characterization, properties, and applications”, Chem. Rev., 108 (9), 3893-3950 (2008).
12 Huang, S.L., Chin, W.K., Yang, W.P., “Viscosity, particle size distribution, and structural investigation of tetramethyloxysilane/2-hydroxyethyl methacrylate sols during the sol-gel process with acid and base catalysts”, J. Poly. Sci., Part B: Polym. Phys., 42 (18), 3476-3486 (2004).
13 Ni, K.F., Shan, G.R., Weng. Z.X., Sheibat-Othman, N., Fevotte, G., Lefebvre, F., Bourgeat-Lami, E., “Synthesis of hybrid core-shell nanoparticles by emulsion (co)polymerization of styrene and γ-methacryloxypropyltrimethoxysilane”, Macromolecules, 38, 7321-7329 (2005).
14 Qu, A.l., Wen, X.F., Pi, P.H., Cheng, J., Yang, Z.R., “Synthesis of composite particles through emulsion polymerization based on silica/fluoroacrylate-siloxane using anionic reactive and nonionic surfactants”, J. Coll. Inter. Sci., 317, 62-69 (2008).
15 Alain, G., Landfester, K., Schorkc, F., Wang, C.P., “Hybrid polymer latexes”, Prog. Polym. Sci., 32 (12), 1439-1461 (2007).
16 Huang, F.M., Zhang, G.W., Hu, C.P., Ying, S.K., “Preparation and characterization of hybrid aqueous dispersions composed of silica sol and poly(styrene-co-acrylate)”, Chin. J. Chem. Eng., 13 (6), 816-823 (2005).
17 Tissot, I., Novat, C., Lefebvre, F., Bourgear-Lami, E., “Hybrid latex particles coated with silica”, Macromolecules, 34 (17), 5737-5739 (2001).
18 Tissot, I., Reymond, J. P., Lefebvre, F., Bourgear-Lami, E., “SiOH-functionalized polystyrene latexes. A step toward the synthesis of hellow silica nanoparticles”, Chem. Mater., 14, 1325-1331 (2002).
19 Luo, C.F., Qu, J.Q., Chen, H.Q., “Synthesis and properties of ambient self-crosslinkable polyacrylate latex with sealed function”, CTESC Journal, 60 (7),1823-1830 (2009).
20 Wang, S.C., Chen, P.C., Yeh, J.T., Chen, K.N., “A new curing agent for self-curable system of aqueous-based PU dispersion”, Reactive & Functional Polymers, 67, 299-311 (2007).
21 Xiao, X.Y., Liu, J.F., “Synthesis and characterization of fluorine-containing polyacrylate emulsion with core-shell structure”, Chin. J. Chem. Eng., 16 (4), 626-630 (2008).
22 Smarsly, B., Garnweitner, G., Assink, R., Jeffrey Brinker, C., “Preparation and characterization of mesostructured polymer-functionalized sol-gel-derived thin films”, Progress Organic Coatings, 47, 393-400 (2003).

Preparation of Organic/Inorganic Hybrid Polymer Emulsions with High Silicon Content and Sol-gel-derived Thin Films

Preparation of Organic/Inorganic Hybrid Polymer Emulsions with High Silicon Content and Sol-gel-derived Thin Films

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