GAO JihuiCHEN GuoqingFU XiaolinDU QianGAO JianminQIN Yukun" /> SO<SUB>2</SUB>对钙基吸收剂吸收NO的作用机理

CIESC Journal

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SO2对钙基吸收剂吸收NO的作用机理

高继慧,陈国庆,付晓林,杜谦,高建民,秦裕琨   

  1. 哈尔滨工业大学燃烧工程研究所
  • 出版日期:2010-11-05 发布日期:2010-11-05

Effect of SO2 on NO removal by calcium hydroxide

GAO JihuiCHEN GuoqingFU XiaolinDU QianGAO JianminQIN Yukun   

  • Online:2010-11-05 Published:2010-11-05

摘要:

针对低温条件下SO2对Ca(OH)2吸收NO的影响进行了实验研究,分析了烟气中O2和H2O对SO2促进Ca(OH)2吸收NO的影响。实验结果表明,当烟气不含SO2时,Ca(OH)2对NO基本无吸收作用;烟气中SO2的存在对NO

Abstract:

The effect of SO2 on NO removal by Ca(OH)2 was investigated at a low temperature. The influence of H2O and O2 on the enhancement effect of SO2 on NO removal was analyzed. The experimental results showed that NO removal was negligible in the absence of SO2. SO2 could enhance NO removal. H2O and O2 have great influence on the enhancement of SO2 on NO removal. NO could not be absorbed by Ca(OH)2 in the absence of O2, even though a high SO2  removal could be attained. SO2 could enhance NO removal when H2O and O2 were present in the flue gas simultaneously. CaSO3, a typical desulfurization reaction product, could not oxidize NO to NO2. The multi-molecular intermediate species, which could decompose to NO2, was not formed from the adsorption of NO, H2O and O2 on the surface of absorbent. There may be some unstable intermediate species formed from the desulfurization reaction, which can accelerate the reaction of NO and O2.