CIESC Journal ›› 2011, Vol. 19 ›› Issue (1): 151-162.
孙长宇, 李文志, 杨新, 李风光, 袁青, 穆亮, 陈俊, 刘蓓, 陈光进
收稿日期:
2010-09-24
修回日期:
2010-11-07
出版日期:
2011-02-28
发布日期:
2011-02-28
通讯作者:
CHEN Guangjin, E-mail: gjchen@cup.edu.cn
基金资助:
SUN Changyu, LI Wenzhi, YANG Xin, LI Fengguang, YUAN Qing, MU Liang, CHEN Jun, LIU Bei, CHEN Guangjin
Received:
2010-09-24
Revised:
2010-11-07
Online:
2011-02-28
Published:
2011-02-28
Supported by:
摘要: It is of great significance to study gas hydrate because of following reasons. (1) Most organic carbon in the earth reserves in the form of natural gas hydrate, which is considered as a potential energy resource for the survival of human being in the future. (2) A series of novel technologies are based on gas hydrate. (3) Gas hydrate may lead to many hazards including plugging of oil/gas pipelines, accelerating global warming up, etc. In this paper, the latest progresses in exploration and exploitation of natural gas hydrate, the development of hydrate-based technologies including gas separation, gas storage, CO2 sequestration via forming hydrate, as well as the prevention of hydrate hazards are reviewed. Additionally, the progresses in the fundamental study of gas hydrate, including the thermodynamics and kinetics are also reviewed. A prospect to the future of gas hydrate research and application is given.
孙长宇, 李文志, 杨新, 李风光, 袁青, 穆亮, 陈俊, 刘蓓, 陈光进. Progress in Research of Gas Hydrate[J]. CIESC Journal, 2011, 19(1): 151-162.
SUN Changyu, LI Wenzhi, YANG Xin, LI Fengguang, YUAN Qing, MU Liang, CHEN Jun, LIU Bei, CHEN Guangjin. Progress in Research of Gas Hydrate[J]. , 2011, 19(1): 151-162.
1 Milkov, A.V., “Global estimates of hydrate-bound gas in marine sediments: how much is really out there?”, Earth-Sci. Rev., 66 (3/4),183-197 (2004). 2 Makogon, Y.F., “Natural gas hydrates-A promising source of energy”, J. Nat. Gas Sci. Eng., 2 (1), 49-59 (2010). 3 Makogon, Y.F., Holditch, S.A., Makogon. T.Y., “Natural gas-hydrates—A potential energy source for the 21st Century”, J. Pet. Sci. Eng., 56 (1-3), 14-31 (2007). 4 Wood, W.T., Hart, P.E., Hutchinson, D.R., Dutta, N., Snyder, F., Coffin, R.B., Gettrust, J.F., “Gas and gas hydrate distribution around seafloor seeps in Mississippi Canyon, Northern Gulf of Mexico, using multi-resolution seismic imagery”, Mar. Petrol. Geol., 25 (9),952-959 (2008). 5 Takahashi, H., Tetsuo, Y., Yoshikazu, T., “Exploration for natural hydrate in Nankai-Trough wells offshore Japan”, J. Japan. Assoc. Petrol. Technol., 66 (6), 652-665 (2001). 6 Collett, T.S., “Energy resource potential of natural gas hydrates”, Am. Assoc.Petrol. Geo., 86 (11), 1971-1992 (2002). 7 Collett, T., Johnson, A., Knapp, C., Boswell, R., Natural Gas Hydrates—Energy Resource Potential and Associated Geologic Hazards, 89 (AAPG Memoir), American Association of Petroleum Geologists, 505-524 (2009). 8 Osadetz, K.G., Chen, Z., “A re-examination of Beaufort Sea-Mackenzie Delta Basin gas hydrate resource potential using a petroleum system approach”, In: Proceedings of the Fifth International Conference on Gas Hydrates, Trondheim, Norway (2005). 9 Walsh, T.P., Stokes, P.J., Singh, P.K., “Characterization and quantification of the methane hydrate resource potential associated with the Barrow Gas Fields”, In: Proceedings of the 6th International Conference on Gas Hydrotes (ICGH), Vancouver, British Columbia, Canada (2008). 10 Xu, W.S., Yu, X.H., Liu, N.N., Liu, W.L., “The development perspective and environmental problems of natural gas hydrates”, Natural Gas Geoscience, 16 (5), 680-683 (2005). (in Chinese) 11 Hao, L., Cui, Y.X., “Resource potential and exploiting prospects of gas hydrate”, Appl. Energy Technol., 7, 5-6 (2009). (in Chinese) 12 Lu, H., Lorenson, T.D., Moudrakovski, I.L., Ripmeester, J.A., Collett, T.S., Hunter, R.B., Ratcliffe, C.I., “The characteristics of gas hydrates recovered from Mount Elbert gas hydrate stratigraphic test well, Alaska North Slope”, Mar.Petrol. Geol., 1-8 (2010). 13 Yao, B.C., “The gas hydrate in the south China sea”, J. Tropical Oceanography, 20 (2), 20-28 (2001). (in Chinese) 14 Zeng, W.P., Zhou, D., “GIS-aided estimation of gas hydrate resources in southern south China sea”, J. Tropical Oceanography, 22 (6), 35-45 (2003). (in Chinese) 15 Jiang, H.Y., Qiao, W.J., Zhong, T.X., Song, X.M., Qi, R.L., An, X.X., “Status and forecast of world’s natural gas hydrate exploration and development”, Sino-Global Energy, 13 (6), 19-25 (2008). (in Chinese) 16 Zhu, Y.H., Zhang, Y.Q., Wen, H.J., Lu, Z.Q., Wang, P.K., “Gas hydrates in the Qilian Mountain permafrost and their basic characteristics”, Acta Gelscientica Sinica, 31 (1), 7-16 (2010). (in Chinese) 17 Xu, S.S., Wang, T., Liu, T.J., Wang, D., Cao, D.Y., “Resource quantity estimation of gas hydrate in Muli coalfield, Qinhai Province”, Coal Geology of China, 21 (9), 1-3 (2009). (in Chinese) 18 Kumar, R., Wu, H.J., Englezos, P., “Incipient hydrate phase equilibrium for gas mixtures containing hydrogen, carbon dioxide and propane”, Fluid Phase Equilibria, 244 (2), 167-171 (2006). 19 Zhang, J.S., Lee, J.W., “Equilibrium of hydrogen + cyclopentane and carbon dioxide + cyclopentane binary hydrates”, J. Chem. Eng. Data,54 (2), 659-661 (2009). 20 Zhang, J.S., Yedlapalli, P., Lee, J.W., “Thermodynamic analysis of hydrate-based pre-combustion capture of CO2 ”, Chem. Eng. Sci., 64 (22), 4732-4736 (2009). 21 Kamata, Y., Yamakoshi, Y., Ebinuma, T., Oyama, H., Shimada, W., Narita, H., “Hydrogen sulfide separation using tetra-n-butyl ammonium bromide semi-clathrate (TBAB) hydrate”, Energy & Fuels, 19 (4), 1717-1722 (2005). 22 Seo, Y., Tajima, H., Yamasaki, A., Takeya, S., Ebinuma,T., Kiyono, F., “A new method for separating HFC-134a from gas mixtures using clathrate hydrate formation”, Environ. Sci. Technol., 38 (17),4635-4639 (2004). 23 Zhang, C.S., Fan, S.S., Liang, D.Q., Guo, K.H., “Effect of additives on formation of natural gas hydrates”, Fuel, 83 (16), 2115-2121 (2004). 24 Sun, C.Y., Chen, G.J., Zhang, L.W., “Hydrate phase equilibrium and structure for (methane + ethane + tetrahydrofuran + water) system”, J. Chem. Thermodynamics, 42 (9), 1173-1179 (2010). 25 Fukumoto, K., Tobe, J., Ohmura, R., Mori, Y.H., “Hydrate formation using water spraying in a hydrophobic gas: A preliminary study”, AIChE J., 47 (8), 1899-1904 (2001). 26 Warzinski, R.P., Riestenberg, D.E., Gabitto, J., Haljasmaa, I.V., Lynn, R.J., Tsouris, C., “Formation and behavior of composite CO2 hydrate particles in a high-pressure water tunnel facility”, Chem. Eng. Sci.,63 (12), 3235-3248 (2008). 27 Szymcek, P., McCallum, S.D., Taboada-Serrano, P., Tsouris, C., “A pilot-scale continuous-jet hydrate reactor”, Chem. Eng. J., 135 (1/2),71-77 (2008). 28 Luo, Y.T., Zhu, J.H., Fan, S.S., Chen, G.J., “Study on the kinetics of hydrate formation in a bubble column”, Chem. Eng. Sci., 62 (4),1000-1009 (2007). 29 Hashemi, S., Macchi, A., Servio, P., “Gas-liquid mass transfer in a slurry bubble column operated at gas hydrate forming conditions”, Chem. Eng. Sci., 64 (16), 3709-3716 (2009). 30 Tajima, H., Nagata, T., Abe, Y., Yamasaki, A., Kiyono, F., Yamagiwa, K., “HFC-134a hydrate formation kinetics during continuous gas hydrate formation with a kenics static mixer for gas separation”, Ind. Eng. Chem. Res., 49 (5), 2525-2532 (2010). 31 Seo, Y.T., Moudrakovski, I.L., Ripmeester, J.A., Lee, J.W., Lee, H., “Efficient recovery of CO2 from flue gas by clathrate hydrate formation in porous silica gels”, Environ. Sci. Technol., 39 (7), 2315-2319 (2005). 32 Zhong, Y., Rogers, R.E., “Surfactant effects on gas hydrate formation”, Chem. Eng. Sci., 55 (19), 4175-4187 (2000). 33 Li, S.F., Fan, S.S., Wang, J.Q., Lang, X.M., Liang, D.Q., “CO2 capture from binary mixture via forming hydrate with the help of tetra-n-butyl ammonium bromide”, J. Natural Gas Chem., 18 (1),15-20 (2009). 34 Zhang, L.W., Chen, G.J., Guo, X.Q., Sun, C.Y., Yang, L.Y., “The partition coefficients of ethane between vapor and hydrate phase for methane plus ethane plus water and methane plus ethane plus THF plus water systems”, Fluid Phase Equilibria, 225 (1/2), 141-144 (2004). 35 Zhang, L.W., Chen, G.J., Sun, C.Y., Ding, Y.M., Yang, L.Y., “The partition coefficients of ethylene between vapor and hydrate phase for methane plus ethylene plus THF plus water systems”, Fluid Phase Equilibria, 245 (2), 134-139 (2006). 36 Zhang, L.W., Chen, G.J., Sun, C.Y., Fan, S.S., Ding, Y.M., Wang, X.L., Yang, L.Y., “The partition coefficients of ethylene between hydrate and vapor for methane + ethylene + water and methane + ethylene + SDS + water systems”, Chem. Eng. Sci., 60 (19),5356-5362 (2005). 37 Sun, C.Y., Ma, C.F., Chen, G.J., Zhang, S.X., “Experimental and simulation of single equilibrium stage separation of (methane + hydrogen) mixtures via forming hydrate”, Fluid Phase Equilibria, 261 (1/2), 85-91 (2007). 38 Linga, P., Kumar, P., Englezos, P., “The clathrate hydrate process for post and pre-combustion capture of carbon dioxide”, J. Hazard. Mater., 149 (3), 625-629 (2007). 39 Linga, P., Adeyemo, A., Englezos, P., “Medium-pressure clathrate hydrate/ membrane hybrid process for postcombustion capture of carbon dioxide”, Environ. Sci. Technol., 42 (1), 315-320 (2008). 40 Nagata, T., Tajima, H., Yamasaki, A., Kiyono, F., Abe, Y., “An analysis of gas separation processes of HFC-134a from gaseous mixtures with nitrogen—Comparison of two types of gas separation methods, liquefaction and hydrate-based methods, in terms of the equilibrium recovery ratio”, Sep. Purif. Technol., 64 (3), 351-356 (2009). 41 Duc, N.H., Chauvy, F., Herri, J.M., “CO2 capture by hydrate crystallization—A potential solution for gas emission of steelmaking industry”, Energy Conversion and Management, 48 (4), 1313-1322 (2007). 42 Makogon, Y.F., Hydrates of Hdrocarbon, Pennwell Publishing Co.,Tulsa, Oklahoma (1997). 43 Gudmundsson, J.S., Khokhar, A.A., Parlaktuna, M., “Storage of natural gas as frozen hydrate”, In: Proceedings of the 67th Annual Technical Conference and Exhibition of Society of Petroleum Engineers (SPE), SPE 24924, Washington, D.C., 699-707 (1990). 44 Gudmundsson, J.S., Parlaktuna, M., Khokhar, A.A., “Storing natural gas as frozen hydrates”, SPE Prod. Facil., 9 (1), 69-73 (1994). 45 Stern, L.A., Circone, S., Kirby, S.H., Durham, W.B., “Anomalous preservation of pure methane hydrate at 1 atm”, J. Phys. Chem. B,105 (9), 1756-1762 (2001). 46 Giavarini, C., Maccioni, F., “Self-preservation at low pressures of methane hydrates with various gas contents”, Ind. Eng. Chem. Res.,43 (20), 6616-6621 (2004). 47 Kuhs, W.F., Genov, G., Satykova, D.K., Hansen, T., “Ice perfection and onset of anomalous preservation of gas hydrates”, Phys. Chem. Chem. Phys., 6, 4917-4920 (2004). 48 Shimada, W., Takeya, S., Kamata, Y., Uchida, T., Nagao, J., Ebinuma, T., Narita, H., “Texture change of ice on anomalously preserved methane clathrate hydrate”, J. Phys. Chem. B, 109 (12), 5802-5807 (2005). 49 Mandal, A., Laik, S., “Effect of the promoter on gas hydrate formation and dissociation”, Energy & Fuels, 22 (4), 2527-2532 (2008). 50 Iwasaki, T., Katoh, Y., Nagamori, S., Takahashi, S., “Continuous natural gas hydrate pellet production (NGHP) by process development unit (PDU)”, In: Proceedings of the Fifth International Conference on Gas Hydrates, Trondheim, Norway,1107-1115 (2005). 51 Takaoki, T., Hirai, K., Kamei, M., Kanda, H., “Study of natural gas hydrate (NGH) carriers”, In: Proceedings of the Fifth International Conference on Gas Hydrates, Trondheim, Norway, 1258-1265 (2005). 52 Ohmura, R., Kashiwazaki, S., Shiota, S., Tsuji, H., Mori, Y.H., “Structure-I and structure-H hydrate formation using water spraying”, Energy & Fuels, 16 (5), 1141-1147 (2002). 53 Takahashi, M., Oonari, H., Yamamoto, Y., “A novel manufacturing method of gas hydrate using the micro-bubble technology”, In: Proceedings of the 4th International Conference on Natural Gas Hydrates, Yokohama, Japan, 825-828 (2002). 54 Stern, L.A., Kirby, S.H., Durham, W.B., “Peculiarities of methane clathrate hydrate formation and solid-state deformation, including possible superheating of water ice”, Science, 273 (5283), 1843-1848 (1996). 55 Takaoki, T., Iwasaki, T., Katoh, Y., Arai, T., Horiguchi, K., “Use of hydrate pellets for transportation of natural gas, Advantage of pellet form of natural gas hydrate in sea transportation”, In: Proceedings of the 4th International Conference on Natural Gas Hydrates, Yokohama, Japan, 982-986 (2002). 56 Karaaslan, U., Parlaktuna, M., “Surfactants as hydrate promoters?”, Energy & Fuels, 14 (5), 1103-1107 (2000). 57 Sun, Z.G., Wang, R.Z., Ma, R.S., Guo, K.H, Fan, S.S., “Natural gas storage in hydrate with the presence of promoters”, Energy Conversion and Management, 44 (17), 2733-2742 (2003). 58 Lee, J., Shin, C., Lee, Y., “Experimental investigation to improve the storage potentials of gas hydrate under the unstirring condition”, Energy & Fuels, 24, 1129-1134 (2010). 59 Rogers, R.E., Zhong, Y., Etheridge, J.A., Arunkumar, R., Pearson, L.E., Hogancamp, T.K., “Micellar gas hydrates storage process”, In: Proceedings of the Fifth International Conference on Gas Hydrates, Trondheim, Norway, 1361-1365 (2005). 60 Pang, W.X., Chen, G.J., Dandekar, A., Sun, C.Y., Zhang, C.L., “Experimental study on the scale-up effect of gas storage in the form of hydrate in a quiescent reactor”, Chem. Eng. Sci., 62 (8), 2198-2208 (2007). 61 Lin, W., Chen, G.J., Sun, C.Y., Guo, X.Q., Wu, Z.K., Liang, M.Y., Chen, L.T., Yang, L.Y., “Effect of surfactant on the formation and dissociation kinetic behavior of methane hydrate”, Chem. Eng. Sci.,59 (21), 4449-4455 (2004). 62 Guo, Y.K., Fan, S.S., Guo, K.H., Chen, Y., “Storage capacity of methane in hydrate using calcium hypochlorite as additive”, In: Proceedings of the Fourth International Conference on Natural Gas Hydrates, Yokohama, Japan, 1040-1043 (2002). 63 Karaaslan, U., Uluneye, E., Parlaktuna, M., “Effect of an anionic surfactant on different type of hydrate structures”, J. Pet. Sci. Eng.,35 (1/2), 49-57 (2002). 64 Ganandran, N., Amin, R., “The effect of hydrotropes on gas hydrates formation”, J. Pet. Sci. Eng., 40 (1/2), 37-46 (2003). 65 Sun, Z.G., Ma, R.S., Wang, R.Z., Guo, K.H., Fan, S.S., “Experimental studying of additives effects on gas storage in hydrates”, Energy & Fuels, 17 (5), 1180-1185 (2003). 66 Ganji, H., Manteghian, M., Zadeh, K.S., Omidkhah, M.R., Mofrad, H.R., “Effect of different surfactants on methane hydrate formation rate, stability and storage capacity”, Fuel, 86 (3), 434-441 (2007). 67 Prado, M.R., Cazares, Y., Janda, K.C., “Toward the efficient production of methane/propane double hydrate”, Ind. Eng. Chem. Res., 48 (11), 5160-5164 (2009). 68 Ganji, H., Manteghian, M., Mofrad, H.R., “Effect of mixed compounds on methane hydrate formation and dissociation rates and storage capacity”, Fuel Process. Technol., 88 (9), 891-895 (2007). 69 Kawamura, T., Sakamoto, Y., Ohtake, M., Yamamoto, Y., Komai, T., Haneda, H., Yoon, J.H., “Dissociation behavior of pellet-shaped methane hydrate in ethylene glycol and silicone oil. Part 1: Dissociation above ice point”, Ind. Eng. Chem. Res., 45 (1), 360-364 (2006). 70 Gudmundsson, J.S., Mork, M., Graff, O.F., “Hydrate non-pipeline technology”, In: Proceedings of the Fourth International Conference on Gas Hydrate, Yokohama, Japan, 997-1002 (2002). 71 Kanda, H., “Economics study on natural gas transportation with natural gas hydrate pellets”, In: 23rd World Gas Conference, Amsterdam (2006). 72 Javanmardi, J., Nasrifar, K., Najibi, S.H., Moshfeghian, M., “Economic evaluation of natural gas hydrate as an alternative for natural gas transportation”, Appl. Therm. Eng., 25 (11/12), 1708-1723 (2005). 73 Nakayama, T., Tomura, S., Ozaki, M., Ohmura, R., Mori, Y.H., “Engineering investigation of hydrogen storage in the form of clathrate hydrates: Conceptual design of hydrate production plants”, Energy & Fuels, 24, 2576-2588 (2010). 74 Mao, W.L., Mao, H.K., Goncharov, A.F., Struzhkin, V.V., Guo, Q.Z., Hu, J.Z., Shu, J.F., Hemley, R.J., Somayazulu, M., Zhao, Y.S., “Hydrogen clusters in clathrate hydrate”, Science, 297 (5990), 2247-2249 (2002). 75 Lee, H., Lee, J.W., Kim, D.Y., Park, J., Seo, Y.T., Zeng, H., Moudrakovski, I.L., Ratcliffe, C.I., Ripmeester, J.A., “Tuning clathrate hydrates for hydrogen storage”, Nature, 434 (7034), 743-746 (2005). 76 Tsuda, T., Ogata, K., Hashimoto, S., Sugahara, T., Moritoki, M., Ohgaki, K., “Storage capacity of hydrogen in tetrahydrothiophene and furan clathrate hydrates”, Chem. Eng. Sci., 64 (19), 4150-4154 (2009). 77 Ogata, K., Tsuda, T., Amano, S., Hashimoto, S., Sugahara, T., Ohgaki, K., “Hydrogen storage in trimethylamine hydrate: Thermodynamic stability and hydrogen storage capacity of hydrogen + trimethylamine mixed semi-clathrate hydrate”, Chem. Eng. Sci., 65 (5), 1616-1620 (2010). 78 Florusse, L.J., Peters, C.J., Schoonman, J., Hester, K.C., Koh, C.A., Dec, S.F., Marsh, K.N., Sloan, E.D., “Stable low-pressure hydrogen clusters stored in a binary clathrate hydrate”, Science, 306 (5695),469-471 (2004). 79 Strobel, T.A., Taylor, C.J., Hester, K.C., Dec, S.F., Koh, C.A., Miller, K.T., Sloan, E.D., “Molecular hydrogen storage in binary THF-H2 clathrate hydrates”, J. Phys. Chem. B, 110 (34), 17121-17125 (2006). 80 Ogata, K., Hashimoto, S., Sugahara, T., Moritoki, M., Sato, H., Ohgaki, K., “Storage capacity of hydrogen in tetrahydrofuran hydrate”, Chem. Eng. Sci., 63 (23), 5714-5718 (2008). 81 Hashimoto, S., Murayama, S., Sugahara, T., Sato, H., Ohgaki, K., “Thermodynamic and Raman spectroscopic studies on H2 + tetrahydrofuran + water and H2 + tetra-n-butyl ammonium bromide + water mixtures containing gas hydrates”, Chem. Eng. Sci., 61 (24),7884-7888 (2006). 82 Chapoy, A., Anderson, R., Tohidi, B., “Low-pressure molecular hydrogen storage in semi-clathrate hydrates of quaternary ammonium compounds”, J. Am. Chem. Soc., 129 (4), 746-747 (2007). 83 Sakamoto, J., Hashimoto, S., Tsuda, T., Sugahara, T., Inoue, Y., Ohgaki, K., “Thermodynamic and Raman spectroscopic studies on hydrogen + tetra-n-butyl ammonium fluoride semi-clathrate hydrates”, Chem. Eng. Sci., 63 (24), 5789-5794 (2008). 84 Hester, K.C., Strobel, T.A., Sloan, E.D., Koh, C.A., Huq, A., Schultz, A.J., “Molecular hydrogen occupancy in binary THF-H2 clathrate hydrates by high resolution neutron diffraction”, J. Phys. Chem. B,110 (29), 14024-14027 (2006). 85 Anderson, R., Chapoy, A., Tohidi, B., “Phase relations and binary clathrate hydrate formation in the system H2 -THF-H2 O”, Langmuir,23 (6), 3440-3444 (2007). 86 Strobel, T.A., Koh, C.A., Sloan, E.D., “Hydrogen storage properties of clathrate hydrate materials”, Fluid Phase Equilibria, 261 (1/2),382-389 (2007). 87 Talyzin, A., “Feasibility of H2 -THF-H2 O clathrate hydrates for hydrogen storage applications”, Int. J. Hydrogen Energy, 33 (1),111-115 (2008). 88 Profio, D.P., Arca, S., Rossi, F., Filipponi, M., “Comparison of hydrogen hydrates with existing hydrogen storage technologies: Energetic and economic evaluations”, Int. J. Hydrogen Energy, 34 (22),9173-9180 (2009). 89 Giavarini, C., Maccioni, F., Politi, M., Santarelli, M.L., “CO2 hydrate: Formation and dissociation compared to methane hydrate”, Energy & Fuels, 21 (6), 3284-3291 (2007). 90 House, K.Z., Schrag, D.P., Harvey, C.F., Lackner, K.S., “Permanent carbon dioxide storage in deep-sea sediments”, Proc. Natl. Acad. Sci. U.S.A., 103 (33), 12291-12295 (2006). 91 Kvamme, B., Graue, A., Buanes, T., Kuznetsova, T., Ersland, G., “Storage of CO2 in natural gas hydrate reservoirs and the effect of hydrate as an extra sealing in cold aquifers”, International Journal of Greenhouse Gas Control, 1 (2), 236-246 (2007). 92 Sloan, E.D., Koh, C.A., Clathrate Hydrates of Natural Gases, 3rd edition, CRC Press, New York (2008). 93 Kelland, M.A., “History of the development of low dosage hydrate inhibitors”, Energy & Fuels, 20 (3), 825-847 (2006). 94 Colle, K.S., Talley, L.D., Longo, J.M., “Method for inhibiting hydroate formation”, U.S. Pat., 0205603 (2006). 95 Leinweber, D., Roesch, A., Feustel, M., “Use of 1-alkyl-5-oxopyrrolidine-3carboxylic esters as gas hydrate inhibitors with improved biodegradabiltiy”, U.S. Pat., 0042747 (2009). 96 Leinweber, D., Roesch, A., Feustel, M., “Use of substituted polyethyleneimines as gas hydrate inhibitors with improved biodegradability”, U.S. Pat., 0054268 (2009). 97 Leinweber, D., Feustel, M., “Polymers and their production and use as gas hydrate inhibitors”, U.S. Pat., 0113878 (2008). 98 Leinweber, D., Feustel, M., “Biologically degradable gas hydrate inhibitors”, U.S. Pat., 0177103 (2008). 99 Leinweber, D., Feustel, M., “Corrosion and gas hydrate inhibitors with an increased biological degradability and a reduced toxicity”, U.S. Pat., 0173663 (2009). 100 Villano, L.D., Kommedal, R., Kelland, M.A., “Class of kinetic hydrate inhibitors with good biodegradability”, Energy & Fuels, 22 (5),3143-3149 (2008). 101 Dahlmann, U., Feustel, M., “Additives for inhibiting the formation of gas hydrates”, U.S. Pat., 0129256 (2007). 102 Dahlmann, U., Feustel, M., “Additives for inhibiting gas hydrate formation”, U.S. Pat., 0173672 (2007). 103 Rivers, G.T., Tian, J., Hackerott, J.A., “Oxazolidinium compounds and hydrate inhibitors”, U.S. Pat., 0130747 (2010). 104 York, J.D., Firoozabadi, A., “Comparing effectiveness of rhamnolipid biosurfactant with a quaternary ammonium salt surfactant for hydrate anti-agglomeration”, J. Phys. Chem. B, 112 (3), 845-851 (2008). 105 Handa, Y.P., Stupin, D., “Thermodynamic properties and dissociation characteristics of methane and propane hydrates in 70-Å-radius silica gel pores”, J. Phys. Chem., 96 (21), 8599-8603 (1992). 106 Anderson, R., Llamedo, M., Tohidi, B., Burgass, R.W., “Experimental measurements of methane and carbon dioxide clathrate hydrate equilibria in mesoporous silica”, J. Phys. Chem. B, 107 (15), 3507-3514 (2003). 107 Seo, Y., Lee, S., Cha, I., Lee, J.D., Lee, H., “Phase equilibria and thermodynamic modeling of ethane and propane hydrates in porous silica gels”, J. Phys. Chem. B, 113 (16), 5487-5492 (2009). 108 Klauda, J.B., Sandler, S.I., “Modeling gas hydrate phase equilibria in laboratory and natural porous media”, Ind. Eng. Chem. Res., 40 (20),4197-4208 (2001). 109 Sun, R., Duan, Z.H., “An accurate model to predict the thermodynamic stability of methane hydrate and methane solubility in marine environments”, Chemical Geology, 244 (1/2), 248-262 (2007). 110 van der Waals, J.H., Platteeuw, J.C., “Clathrate solutions”, Advances in Chemical Physics, 2 (1), 1-57 (1959). 111 Chen, G.J., Guo, T.M., “A new approach to gas hydrate modeling”, Chem. Eng. J., 71 (8), 145-151 (1998). 112 Chen, L.T., Sun, C.Y., Chen, G.J., Nie, Y.Q., “Thermodynamics model of predicting gas hydrate in porous media based on reaction-adsorption two-step formation mechanism”, Ind. Eng. Chem. Res., 49 (8), 3936-3943 (2010). 113 Kang, S.P., Lee, H., “Recovery of CO2 from flue gas using gas hydrate: Thermodynamic verification through phase equilibrium measurements”, Environ. Sci. Technol., 34 (20), 4397-4400 (2000). 114 Hashimoto, S., Murayama, S., Sugahara, T., Ohgaki, K., “Phase equilibria for H2 plus CO2 plus tetrahydrofuran plus water mixtures containing gas hydrates”, J. Chem. Eng. Data, 51 (5), 1884-1886 (2006). 115 Strobel, T.A., Koh, C.A., Sloan, E.D., “Thermodynamic predictions of various tetrahydrofuran and hydrogen clathrate hydrates”, Fluid Phase Equilibria, 280 (1/2), 61-67 (2009). 116 Seo, Y., Kang, S.P., Lee, S., Lee, H., “Experimental measurements of hydrate phase equilibria for carbon dioxide in the presence of THF, propylene oxide, and 1,4-dioxane”, J. Chem. Eng. Data, 53 (12),2833-2837 (2008). 117 Makino, T., Yamamoto, T., Nagata, K., Sakamoto, H., Hashimoto, S., Sugahara, T., Ohgaki, K., “Thermodynamic stabilities of tetra-n-butyl ammonium chloride + H2 , N2 , CH4 , CO2 , or C2H2 semiclathrate hydrate systems”, J. Chem. Eng. Data, 55 (2), 839-841 (2010). 118 Sun, X., Mohanty, K.K., “Kinetic simulation of methane hydrate formation and dissociation in porous media”, Chem. Eng. Sci., 61 (11), 3476-3495 (2006). 119 Yan, L.J., Chen, G.J., Pang, W.X., Liu, J., “Experimental and modeling study on hydrate formation in wet activated carbon”, J. Phys. Chem. B, 109 (12), 6025-6030 (2005). 120 Saha, D., Deng, S.G., “Accelerated formation of THF-H2 clathrate hydrate in porous media”, Langmuir, 26 (11), 8414-8418 (2010). 121 Kang, S.P., Lee, J.W., “Kinetic behaviors of CO2 hydrates in porous media and effect of kinetic promoter on the formation kinetics”, Chem. Eng. Sci., 65 (5), 1840-1845 (2010). 122 Kang, S.P., Seo, Y., Jang, W., “Kinetics of methane and carbon dioxide hydrate formation in silica gel pores”, Energy & Fuels, 23 (7),3711-3715 (2009). 123 Sun, C.Y., Chen, G.J., Ma, C.F., Huang, Q., Luo, H., Li, Q.P., “The growth kinetics of hydrate film on the surface of gas bubble suspended in water or aqueous surfactant solution”, Journal of Crystal Growth, 306 (2), 491-499 (2007). 124 Ribeiro, C.P., Lage, P.L.C., “Modelling of hydrate formation kinetics: State-of-the-art and future directions”, Chem. Eng. Sci., 63 (8),2007-2034 (2008). 125 Nada, H., “Anisotropy in growth kinetics of tetrahydrofuran clathrate hydrate: A molecular dynamics study”, J. Phys. Chem. B, 113 (14), 4790-4798 (2009). 126 Gayet, P., Dicharry, C., Marion, G., Graciaa, A., Lachaise, J., Nesteroy, A., “Experimental determination of methane hydrate dissociation curve up to 55 MPa by using a small amount of surfactants as hydrate promoter”, Chem. Eng. Sci., 60 (21), 5751-5758 (2005). 127 Zhang, J.S., Lee, S.Y., Lee, J.W., “Kinetics of methane hydrate formation from SDS solution”, Ind. Eng. Chem. Res., 46 (19),6353-6359 (2007). 128 Shimada, W., Ebinuma, T., Oyama, H., Kamata, Y., Narita. H., “Free-growth forms and growth kinetics of tetra-n-butyl ammonium bromide semi-clathrate hydrate crystals”, J. Crystal Growth, 274 (1/2), 246-250 (2005). 129 Dalmazzone, D., Kharrat, M., Lachet, V., Fouconnier, B., Clausse, D., “DSC and PVT measurement methane and trichlorofluoromethane hydrate dissociation equilibria”, J. Therm. Anal. Cal., 70 (2), 493-505 (2002). 130 Dalmazzone, D., Hamed, N., Dalmazzone, C., Rousseau, L., “Application of high pressure DSC to the kinetics of formation of methane hydrate in water-in-oil emulsion”, J. Therm. Anal. Cal., 85 (2),361-368 (2006). 131 Jakobsen, T., Folger , K., “Dielectric measurements of gas hydrate formation in water-in-oil emulsions using open-ended coaxial probes”, Meas. Sci. Technol., 8 (9), 1006-1015 (1997). 132 Aichele, C.P., Chapman, W.G., Rhyne, L.D., Subramani, H.J., Montesi, A., Creek, J.L., House, W., “Nuclear magnetic resonance analysis of methane hydrate formation in water-in-oil emulsions”, Energy & Fuels, 23 (1), 835-841 (2009). 133 Boxall, J.A., Greaves, D.P., Mulligan, J., Koh, C.A., Sloan, E.D., “Gas hydrate formation and dissociation from water-in-oil emulsions studied using PVM and FBRM particle size analysis”, In: Proceedings of the 6th International Conference on Gas Hydrate, Vancouver, British Columbia, Canada (2008). 134 Palermo, T., Arla, D., Borregales, M., Dalmazzone, C., Rousseau, L., “Study of the agglomeration between hydrate particles in oil using differential scanning calorimetry (DSC)”, In: Proceedings of Fifth International Conference on Gas Hydrates, Trondheim, Norway, 1,332-339 (2005). 135 Dalmazzone, D., Hamed, N., Dalmazzone, C., “DSC measurements and modelling of the kinetics of methane hydrate formation in water-in-oil emulsion”, Chem. Eng. Sci., 64 (9), 2020-2026 (2009). 136 Dalmazzone, D., Hamed, N., Clausse, D., Pezron, I., Luong, A.T., Dalmazzone, C., “Study of the kinetics of formation of trichlorofluoromethane hydrates and methane hydrates in water-in-oil emulsion by microcalorimetry”, In: Proceedings of the 6th International Conference on Gas Hydrate, Vancouver, British Columbia, Canada (2008). 137 Lee, J., Park, S., Sung, W., “An experimental study on the productivity of dissociated gas from gas hydrate by depressurization scheme”, Energy Conversion and Management, 51 (12), 2510-2515 (2010). 138 Zhou, Y., Castaldi, M.J., Yegulalp, T.M., “Experimental investigation of methane gas production from methane hydrate”, Ind. Eng. Chem. Res., 48 (6), 3142-3149 (2009). 139 Oyama, H., Konno, Y., Masuda, Y., Narita, H., “Dependence of depressurization-induced dissociation of methane hydrate bearing laboratory cores on heat transfer”, Energy & Fuels, 23, 4995-5002 (2009). 140 Selim, M.S., Sloan, E.D., “Hydrate dissociation in sediments”, SPE Reserv. Eng., 5 (2), 245-251 (1990). 141 Kamata, Y., Ebinuma, T., Omura, R., Minagawa, H., Narita, H., Masuda, Y., Konno, Y., “Decomposition experiment of methane hydrate sediment by thermal recovery method”, In: Proceedings of the Fifth International Conference on Gas Hydrates, Trondheim, Norway,81-85 (2005). 142 Li, X.S., Wan, L.H., Li, G., Li, Q.P., Chen, Z.Y., Yan, K.F., “Experimental investigation into the production behavior of methane hydrate in porous sediment with hot brine stimulation”, Ind. Eng. Chem. Res., 47 (23), 9696-9702 (2008). 143 Linga, P., Haligva, C., Nam, S.C., Ripmeester, J.A., Englezos, P., “Recovery of methane from hydrate formed in a variable volume bed of silica sand particles”, Energy & Fuels, 23 (11), 5508-5516 (2009). 144 Lee, J., “Experimental study on the dissociation behavior and productivity of gas hydrate by brine injection scheme in porous rock”, Energy & Fuels, 24, 456-463 (2010). 145 Nihous, G.C., Kuroda, K., Lobos-Gonzalez, J.R., Kurasaki, R.J., Masutani, S.M., “An analysis of gas hydrate dissociation in the presence of thermodynamic inhibitors”, Chem. Eng. Sci., 65 (5),1748-1761 (2010). 146 Moridis, G.J., Collett, T.S., Boswell, R., Kurihara, M., Reagan, M.T., Koh, C., Sloan, E.D., “Toward production from gas hydrates: current status, assessment of resources, and simulation-based evaluation of technology and potential”, SPE Reservoir Evaluation & Engineering., 12 (5), 745-771 (2009). |
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