Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

CIESC Journal ›› 2011, Vol. 19 ›› Issue (1): 163-168.

Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

舒庆^1,2, 高继贤¹, 廖玉会¹, 王金福¹

1. Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China;
2. School of Material and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

收稿日期:2010-06-21 修回日期:2010-12-01 出版日期:2011-02-28 发布日期:2011-02-28
通讯作者: E-mail: wangjf@flotu.org

Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

SHU Qing^1,2, GAO Jixian¹, LIAO Yuhui¹, WANG Jinfu¹

1. Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China;
2. School of Material and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

Received:2010-06-21 Revised:2010-12-01 Online:2011-02-28 Published:2011-02-28

摘要/Abstract

摘要： The kinetics of simultaneous transesterification and esterification with a carbon-based solid acid catalyst was studied.Two solid acid catalysts were prepared by the sulfonation of carbonized vegetable oil asphalt and petroleum asphalt.These catalysts were characterized on the basis of elemental analysis,acidity site concentration,the Brunauer-Emmett-Teller(BET)surface area and pore size.The kinetic parameters with the two catalysts were determined,and the reaction system can be described as a pseudo homogeneous catalyzed reaction.All the forward and reverse reactions follow second order kinetics.The calculated concentration values from the kinetic equations are in good agreement with experimental values.

关键词: biodiesel, carbon-based solid acid catalyst, heterogeneous catalysis, simultaneous transesterification and esterification reaction, kinetics

Abstract: The kinetics of simultaneous transesterification and esterification with a carbon-based solid acid catalyst was studied.Two solid acid catalysts were prepared by the sulfonation of carbonized vegetable oil asphalt and petroleum asphalt.These catalysts were characterized on the basis of elemental analysis,acidity site concentration,the Brunauer-Emmett-Teller(BET)surface area and pore size.The kinetic parameters with the two catalysts were determined,and the reaction system can be described as a pseudo homogeneous catalyzed reaction.All the forward and reverse reactions follow second order kinetics.The calculated concentration values from the kinetic equations are in good agreement with experimental values.

Key words: biodiesel, carbon-based solid acid catalyst, heterogeneous catalysis, simultaneous transesterification and esterification reaction, kinetics

舒庆, 高继贤, 廖玉会, 王金福. Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst[J]. CIESC Journal, 2011, 19(1): 163-168.

SHU Qing, GAO Jixian, LIAO Yuhui, WANG Jinfu. Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst[J]. , 2011, 19(1): 163-168.

参考文献

1 Sharma, Y.C., Singh, B., Upadhyay, S.N., “Advancements in development and characterization of biodiesel: A review”, Fuel, 87,2355-2373 (2008).
2 Gerpen, J.V., “Biodiesel processing and production”, Fuel. Process. Technol., 86, 1097-1107 (2005).
3 Shu, Q., Zhang, Q., Xu, G.H., Nawaz, Z., Wang, D.Z., Wang, J.F., “Synthesis of biodiesel from cottonseed oil and methanol using a carbon-based solid acid catalyst”, Fuel. Process. Technol., 90,1002-1008 (2009).
4 Vicente, G., Martinez, M., Aracil, J.A., “Comparative study of vegetable oils for biodiesel production in spain”, Energy. Fuels., 20,394-398 (2006).
5 Shu, Q., Nawaz, Z., Gao, J.X., Liao, Y.H., Zhang, Q., Wang, D.Z., Wang, J. F., “Synthesis of biodiesel from waste oil feedstocks using a carbon-based solid acid catalyst: Reaction and separation”, Bioresour. Technol., 101, 5374-5384 (2010).
6 Han, M.H., Yi, W.L., Wu, Q., Liu, Y., Hong, Y.C., Wang D.Z., “Preparation of biodiesel from waste oils catalyzed by a Br nsted acidic ionic liquid”, Bioresour. Technol., 100, 2308-2310 (2009).
7 Zhang, J.J., Jiang, L.F., “Acid-catalyzed esterification of zanthoxylum bungeanum seed oil with high free fatty acids for biodiesel production”, Bioresour. Technol., 99, 8995-8998 (2008).
8 Felizardo, P., Correia, M.J.N., Raposo, I., “Production of biodiesel from waste frying oils”, Waste. Manage., 26, 487-494 (2006).
9 Lotero, E., Liu, Y.J., Lopez, D.E., Suwannakarn, K., Bruce, D.A., Goodwin, J.G., “Synthesis of biodiesel via acid catalysis”, Ind. Eng. Chem. Res., 44, 5353-5363 (2005).
10 Toda, M., Takagaki, A., Okamura, M., “Biodiesel made with sugar catalyst”, Nature, 438, 178 (2005).
11 Takagaki, A., Toda, M., Okamura, M., “Esterification of higher fatty acids by a novel strong solid acid”, Catal. Today, 116, 157-167 (2006).
12 Mo, X.H., Lotero, E., Lu, C.Q., “A novel sulfonated carbon composite solid acid catalyst for biodiesel synthesis”, Catal. Lett., 123, 1-6 (2008).
13 Shu, Q., zhang, Q., Xu, G.H., Wang, D.Z., Wang, J.F., “Preparation of biodiesel using s-MWCNT catalysts and the coupling of reaction and separation”, Food. Bioprod. Process., 87, 164-170 (2009).
14 Zong, M.H., Duan, Z.Q., Lou, W.Y., Smith, T.J., Wu, H., “Preparation of a sugar catalyst and its use for highly efficient production of biodiesel”, Green. Chem., 9, 434-437 (2007).
15 Minamia, E., Saka, S., “Kinetics of hydrolysis and methyl esterification for biodiesel production in two-step supercritical methanol process”, Fuel, 85, 2479-2483 (2006).
16 Tesser, R., Serio, M.D., Guida, M., “Kinetics of oleic acid esterification with methanol in the presence of triglycerides”, Ind. Eng. Chem. Res., 44, 7978-7982 (2005).
17 Freedman, B., Butterfield, R.O., Pryde, E.H., “Transesterification kinetics of soybean oil”, J. Am. Oil. Chem. Soc., 63, 1375-1380 (1986).
18 Noureddini, H., Zhu, D., “Kinetics of soybean oil”, J. Am. Oil. Chem. Soc., 74, 1457-1463 (1997).
19 Gan, M.Y., Pan, D., Ma, L., Yue, E., Hong, J.B., “The kinetics of the esterification of free fatty acids in waste cooking oil using Fe₂(SO₄)₃/C catalyst”, Chin. J. Chem. Eng., 17, 83-87 (2009).
20 Chen, H., Wang, J.F., “Kinetics of KOH catalyzed tranesterification of cottonseed oil for biodiesel production”, J. Chem. Ind. Eng. (China), 56, 1971-1974 (2005). (in Chinese)

[1]	熊春华, 朱京妃, 沈忱, 陈青. D72树脂对镨（III）的吸附性能[J]. Chinese Journal of Chemical Engineering, 2012, 20(5): 823-830.
[2]	刘颖颖, 鲁厚芳, 蒋炜, 李东升, 刘世界, 梁斌. 微量酸催化麻疯树籽油制备生物柴油[J]. Chinese Journal of Chemical Engineering, 2012, 20(4): 740-746.
[3]	A.P. Mathews, K.K. Panda. 多孔电极臭氧发生器氧化废水中有机物的吸收和反应动力学分析[J]. CIESC Journal, 2012, 20(3): 417-425.
[4]	谢艳新, 侯丽丽, 杨倩, 蒋登高. AB-8树脂吸附反式1,2-环己二醇热力学和动力学[J]. CIESC Journal, 2012, 20(2): 277-283.
[5]	侯宝林, 张海英, 李洪钟, 朱庆山. 氢气还原氧化铁动力学的研究[J]. CIESC Journal, 2012, 20(1): 10-17.
[6]	李效红, 赵保卫, 朱琨, 郝学奎. Removal of Nitrophenols by Adsorption Using β-Cyclodextrin Modified Zeolites[J]. CIESC Journal, 2011, 19(6): 938-943.
[7]	孙晓英, 赵雪冰, 杜伟, 刘德华. Kinetics of Formic Acid-autocatalyzed Preparation of Performic Acid in Aqueous Phase[J]. CIESC Journal, 2011, 19(6): 964-971.
[8]	Ludovic Montastruc, 刘涛, Iordan Nikov, Pascal Floquet, Serge Domenech. Integrated Process for Production of Surfactin(III)Modeling of Adsorption Column[J]. CIESC Journal, 2011, 19(3): 357-364.
[9]	廖列文, 岳航勃, 崔英德. Crosslink Polymerization Kinetics and Mechanism of Hydrogels Composed of Acrylic Acid and 2-Acrylamido-2-methylpropane Sulfonic Acid[J]. CIESC Journal, 2011, 19(2): 285-291.
[10]	杨传鑫, 颜学峰. A Fuzzy-based Adaptive Genetic Algorithm and Its Case Study in Chemical Engineering[J]. CIESC Journal, 2011, 19(2): 299-307.
[11]	孙长宇, 李文志, 杨新, 李风光, 袁青, 穆亮, 陈俊, 刘蓓, 陈光进. Progress in Research of Gas Hydrate[J]. CIESC Journal, 2011, 19(1): 151-162.
[12]	蔡双飞, 王利生. Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO₃H-functional Brφnsted Acidic Ionic Liquid as Catalyst[J]. CIESC Journal, 2011, 19(1): 57-63.
[13]	刘景明, 孙冬冬, 刘慧, 聂英斌, 朱志荣. Biodegradation Kinetics for Pre-treatment of Klebsiella pneumoniae Waste with Autothermal Thermophilic Aerobic Digestion[J]. CIESC Journal, 2010, 18(6): 905-909.
[14]	徐程浩, 汪芳, 刘代俊, 陈伟. Effect of Additive EDTA on Crystallization Process of Magnesium Hydroxide Precipitation[J]. CIESC Journal, 2010, 18(5): 761-766.
[15]	粟海锋, 刘怀坤, 王凡, 吕小艳, 文衍宣. Kinetics of Reductive Leaching of Low-grade Pyrolusite with Molasses Alcohol Wastewater in H₂SO₄[J]. CIESC Journal, 2010, 18(5): 730-735.

Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价