Pervaporation Separation of Butanol-Water Mixtures Using Polydimethylsiloxane/Ceramic Composite Membrane

CIESC Journal ›› 2011, Vol. 19 ›› Issue (1): 40-44.

Pervaporation Separation of Butanol-Water Mixtures Using Polydimethylsiloxane/Ceramic Composite Membrane

刘公平, 侯丹, 卫旺, 相里粉娟, 金万勤

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China

收稿日期:2010-05-25 修回日期:2010-11-07 出版日期:2011-02-28 发布日期:2011-02-28
通讯作者: JIN Wanqin, E-mail: wqjin@njut.edu.cn
基金资助:
Supported by the National Basic Research Program of China(2009CB623406);the National Natural Science Foundation of China(20990222);the Natural Science Foundation of Jiangsu Province(SBK200930313);the“Six Kinds of Important Talents”Program of Jiangsu Province(2007007)

Pervaporation Separation of Butanol-Water Mixtures Using Polydimethylsiloxane/Ceramic Composite Membrane

LIU Gongping, HOU Dan, WEI Wang, XIANGLI Fenjuan, JIN Wanqin

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China

Received:2010-05-25 Revised:2010-11-07 Online:2011-02-28 Published:2011-02-28
Supported by:
Supported by the National Basic Research Program of China(2009CB623406);the National Natural Science Foundation of China(20990222);the Natural Science Foundation of Jiangsu Province(SBK200930313);the“Six Kinds of Important Talents”Program of Jiangsu Province(2007007)

摘要/Abstract

摘要： Pervaporation has attracted considerable interest owing to its potential application in recovering biobutanol from biomass acetone-butanol-ethanol(ABE)fermentation broth.In this study,butanol was recovered from its aqueous solution using a polydimethylsiloxane(PDMS)/ceramic composite pervaporation membrane.The effects of operating temperature,feed concentration,feed flow rate and operating time on the membrane pervaporation performance were investigated.It was found that with the increase of temperature or butanol concentration in the feed, the total flux through the membrane increased while the separation factor decreased slightly.As the feed flow rate increased,the total flux increased gradually while the separation factor changed little.At 40℃ and 1%(by mass) butanol in the feed,the total flux and separation factor of the membrane reached 457.4 g·m²·h^-1 and 26.1,respectively.The membrane with high flux is suitable for recovering butanol from ABE fermentation broth.

关键词: pervaporation, butanol, PDMS, ceramic, composite membrane

Abstract: Pervaporation has attracted considerable interest owing to its potential application in recovering biobutanol from biomass acetone-butanol-ethanol(ABE)fermentation broth.In this study,butanol was recovered from its aqueous solution using a polydimethylsiloxane(PDMS)/ceramic composite pervaporation membrane.The effects of operating temperature,feed concentration,feed flow rate and operating time on the membrane pervaporation performance were investigated.It was found that with the increase of temperature or butanol concentration in the feed, the total flux through the membrane increased while the separation factor decreased slightly.As the feed flow rate increased,the total flux increased gradually while the separation factor changed little.At 40℃ and 1%(by mass) butanol in the feed,the total flux and separation factor of the membrane reached 457.4 g·m²·h^-1 and 26.1,respectively.The membrane with high flux is suitable for recovering butanol from ABE fermentation broth.

Key words: pervaporation, butanol, PDMS, ceramic, composite membrane

刘公平, 侯丹, 卫旺, 相里粉娟, 金万勤. Pervaporation Separation of Butanol-Water Mixtures Using Polydimethylsiloxane/Ceramic Composite Membrane[J]. CIESC Journal, 2011, 19(1): 40-44.

LIU Gongping, HOU Dan, WEI Wang, XIANGLI Fenjuan, JIN Wanqin. Pervaporation Separation of Butanol-Water Mixtures Using Polydimethylsiloxane/Ceramic Composite Membrane[J]. , 2011, 19(1): 40-44.

参考文献

1 Schoutens, G.H., Groot, W.J., “Economic-feasibility of the production of iso-propanol-butanol-ethanol fuels from whey permeate”, Process Biochem., 20, 117-121 (1985).
2 Ezeji, T.C., Qureshi, N., Blaschek, H.P., “Acetone butanol ethanol (ABE) production from concentrated substrate: reduction in substrate inhibition by fed-batch technique and product inhibition by gas stripping”, Appl. Microbiol. Biot., 63, 653-658 (2004).
3 Qureshi, N., Ezeji, T.C., “Butanol, ‘a superior biofuel’ production from agricultural residues (renewable biomass): recent progress in technology”, Biofuels Bioprod. Biorefin., 2, 319-330 (2008).
4 Yang, X.P., Tsao, G.T., “Enhanced acetone-butanol fermentation using repeated fed-batch operation coupled with cell recycle by membrane and simultaneous removal of inhibitory products by adsorption”, Biotechnol. Bioeng., 47, 444-450 (1995).
5 Yang, X.P., Tsai, G.J., Tsao, G.T., “Enhancement of in-situ adsorption on the acetone-butanol fermentation by clostridium-acetobutylicum”, Sep. Technol., 4, 81-92 (1994).
6 Ezeji, T.C., Qureshi, N., Blaschek, H.P., “Production of acetone, butanol and ethanol by Clostridium beijerinckii BA101 and in situ recovery by gas stripping”, World J. Microb. Biot., 19, 595-603 (2003).
7 Ezeji, T.C., Karcher, P.M., Qureshi, N., Blaschek, H.P., “Improving performance of a gas stripping-based recovery system to remove butanol from Clostridium beijerinckii fermentation”, Bioproc. Biosyst. Eng., 27, 207-214 (2005).
8 Friedl, A., Qureshi, N., Maddox, I.S., “Continuous acetone-butanol-ethanol (ABE) fermentation using immobilized cells of Clostridium acetobutylicum in a packed-bed reactor and integration with product removal by pervaporation”, Biotechnol. Bioeng., 38, 518-527 (1991).
9 Favre, E., Nguyen, Q.T., Bruneau, S., “Extraction of 1-butanol from aqueous solutions by pervaporation”, J. Chem. Technol. Biot., 65,221-228 (1996).
10 Groot, W.J., Vandenoever, C.E., Kossen, N., “Pervaporation for simultaneous product recovery in the butanol isopropanol batch fermentation”, Biotechnol. Lett., 6, 709-714 (1984).
11 Boddeker, K.W., Bengtson, G., Pingel, H., “Pervaporation of isomeric butanols”, J. Membr. Sci., 54, 1-12 (1990).
12 Fadeev, A.G., Selinskaya, Y.A., Kelley, S.S., Meagher, M.M., Litvinova, E.G., Khotimsky, V.S., Volkov, V.V., “Extraction of butanol from aqueous solutions by pervaporation through poly(1-trimethylsilyl-1-propyne)”, J. Membr. Sci., 186, 205-217 (2001).
13 Huang, J., Meagher, M.M., “Pervaporative recovery of n-butanol from aqueous solutions and ABE fermentation broth using thin-film silicalite-filled silicone composite membranes”, J. Membr. Sci., 192,231-242 (2001).
14 Xiangli, F.J., Chen, Y.W., Jin, W.Q., Xu, N.P., “Polydimethylsiloxane (PDMS)/ceramic composite membrane with high flux for pervaporation of ethanol-water mixtures”, Ind. Eng. Chem. Res., 46, 2224-2230 (2007).
15 Xiangli, F.J., Wei, W., Chen, Y.W., Jin, W.Q., Xu, N.P., “Optimization of preparation conditions for polydimethylsiloxane (PDMS)/ ceramic composite pervaporation membranes using response surface methodology”, J. Membr. Sci., 311, 23-33 (2008).
16 Xu, R., Liu, G.P., Dong, X.L., Jin, W.Q., “Pervaporation separation of n-octane/thiophene mixtures using polydimethylsiloxane/ceramic composite membranes”, Desalination, 258, 106-111 (2010).
17 Hijon, N., Manzano, M., Salinas, A.J., Vallet-Regi, M., “CaO-SiO₂ -PDMS coatings on Ti6Al4V substrates”, Chem. Mater., 17, 1591-1596 (2005).
18 Feng, X.S., Huang, R.Y.M., “Estimation of activation energy for permeation in pervaporation processes”, J. Membr. Sci., 118, 127-131 (1996).
19 Chen, Y.W., Xiangli, F.J., Jin, W.Q., Xu, N.P., “Organic-inorganic composite pervaporation membranes prepared by self-assembly of polyelectrolyte multilayers on macroporous ceramic supports”, J. Membr. Sci., 302, 78-86 (2007).
20 Jonquieres, A., Fane, A., “Filled and unfilled composite GFT PDMS membranes for the recovery of butanols from dilute aqueous solutions: influence of alcohol polarity”, J. Membr. Sci., 125, 245-255 (1997).
21 Vrana, D.L., Meagher, M.M., Hutkins, R.W., Duffield, B., “Pervaporation of model acetone-butanol-ethanol fermentation product solutions using polytetrafluoroethylene membranes”, Sep. Sci. Technol., 28, 2167-2178 (1993).
22 Liu, F.F., Liu, L., Feng, X.S., “Separation of acetone-butanol-ethanol (ABE) from dilute aqueous solutions by pervaporation”, Sep. Purif. Technol., 42, 273-282 (2005).
23 Jitesh, K., Pangarkar, V.G., Niranjan, K., “Pervaporative stripping of acetone, butanol and ethanol to improve ABE fermentation”, Bioseparation, 9, 145-154 (2000).

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Pervaporation Separation of Butanol-Water Mixtures Using Polydimethylsiloxane/Ceramic Composite Membrane

Pervaporation Separation of Butanol-Water Mixtures Using Polydimethylsiloxane/Ceramic Composite Membrane

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