CIESC Journal

• 材料科学与技术 • 上一篇    下一篇

石蜡微胶囊型相变储能材料制备及表征

孙 凯,张步宁,晏凤梅,尹国强,崔英德   

  1. 仲恺农业工程学院绿色化工研究所,广东 广州 510225
  • 出版日期:2011-12-05 发布日期:2012-03-02

Preparation and characterization of microcapsule with paraffin phase change materials for energy storage

SUN Kai,ZHANG Buning,YAN Fengmei,YIN Guoqiang,CUI Yingde   

  1. Institute of Green Chemical Engineering,Zhongkai University of Agriculture and Engineering,Guangzhou 510225,Guangdong,China
  • Online:2011-12-05 Published:2012-03-02

摘要:

采用原位聚合法以30#石蜡为芯材、密胺树脂(MF)为囊材,制备了具有相变储热功能的微胶囊,并将所制得微胶囊添加到石膏板中。采用SEMFTIRDSCTG等手段对微胶囊外观形貌、化学结构和热性能进行了表征,并测试了石膏板储能性能。结果表明:制得微胶囊中石蜡平均含量约为50.4%,相变温度和相变潜热分别30 108.7 J/g;微胶囊表面光滑有突起,粒径在1020 μm;具有较好的外观结构和良好的热稳定性,能增强石膏板的保温性能

Abstract:

Microencapsulated phase change materials with 30# paraffin as core material and melamine resin as capsule material were prepared by in-situ polymerization and were added to gypsum boards. The morphologychemical structure and thermal performance of microcapsules were characterized by SEMFTIRDSC and TG methodsand the performance of gypsum board for energy storage was tested. The results showed thatparaffin content in the microcapsules was about 50.4%and the phase transition temperature and enthalpy values were 30 and 108.7 J/g respectively. The microcapsule appearance is a smooth protruding surfaceand particle sizes were between 1020 μm. Microcapsules with good structure and thermal stability can enhance the energy storage performance of gypsum board.