化工学报 ›› 2011, Vol. 62 ›› Issue (10): 2945-2950.

• 能源和环境工程 • 上一篇    下一篇

防溴型环氧树脂电路板热解动力学分析

王芳, 刘玉卿,海热提   

  • 出版日期:2011-10-05 发布日期:2011-10-05

  • Online:2011-10-05 Published:2011-10-05

Abstract:

Use of antiBr printed circuit boards(PCBs) made epoxy resin is more and more popular and can generate large amount of solid wasteTheir thermostability and characteristics of pyrolysis reaction including kinetics was investigated in atmosphere of argon using thermogravimetric(TG)analysis at various hearting rates(5,10,20,30℃·min-1).The kinetic parameters of pyrolysis reaction including activation energy E were determined by Kissinger’s differentiation and FlynnWallOzawa’s integration methodsA study by CoatsRedfern method indicated that the Valensi equation was a good approximation of the thermal decomposition reaction kinetics, the order of decomposition reaction was 2, the average activation energy E160.62 kJ·mol-1, and the thermal decomposition mechanism function α+(1-αln(1-α).