胶原纤维负载铁Fe(Ⅲ)<SPAN style=

• 催化、动力学与反应器 • 上一篇下一篇

胶原纤维负载铁Fe(Ⅲ) 焦利敏 1, 2, 黄鑫2, 廖学品2, 石碧2

1广州狮岭皮革皮具产业研究中心博士后科研工作站, 广东广州 510850； 2四川大学制革清洁技术国家工程实验室，四川成都 610065

`出版日期:`2011-12-05 `发布日期:`2011-12-05

Catalytic degradation of dimethyl phthalate by photo-assisted Fe(Ⅲ) immobilized collagen fiber

<JIAO Limin1, 2, HUANG Xin2, LIAO Xuepin2, SHI Bi2

`Online:`2011-12-05 `Published:`2011-12-05

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摘要：

将Fe(Ⅲ)负载在胶原纤维上制备负载型铁催化剂(FeCF)，并研究了该催化剂对邻苯二甲酸二甲酯（DMP）的非均相Fenton催化降解性能。结果表明：与FeCF/H₂O₂/暗光体系、FeCF/UV体系和H₂O₂/UV体系相比，FeCF/H₂O₂/UV体系对DMP的降解率明显提高。H₂O₂

Abstract:

Fe(Ⅲ)immobilized collagen fiber(FeCF）catalyst was prepared and its photo-assisted catalytic degradation behaviors to dimethyl phthalate(DMP）were investigated.Compared with FeCF/ H₂O₂/dark, FeCF/UV and H₂O₂/UV reaction system, FeCF/ H₂O₂/UV is more effective for degradation of DMP.It is found that the H₂O₂ concentration and temperature are the main factors that greatly influence the degradation performance of DMP.Under irradiation of UV 254 nm, 100% degradation of DMP can be obtained within 30 min when the dosage of FeCF and H₂O₂ is 1.0 g·L^-1 and 1.0 mmol·L^-1 respectively.In addition, FeCF is effective for the degradation of DMP in the wide pH range of 3.07 to 7.96, and its photo-assisted catalytic degradation activity has no obvious decrease in 5 cycles.So, there is a potential for FeCF to treat DMP pollutant.

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10.3969/j.issn.0438-1157.2011.12.017

焦利敏 1, 2, 黄鑫2, 廖学品2, 石碧2. 胶原纤维负载铁Fe(Ⅲ)Catalytic degradation of dimethyl phthalate by photo-assisted Fe(Ⅲ) immobilized collagen fiber[J]. .

Catalytic degradation of dimethyl phthalate by photo-assisted Fe(Ⅲ) immobilized collagen fiber

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