摘要：

以双酚A和溴丙炔为原料，采用相转移催化剂，合成了二丙炔基双酚A醚。利用红外、核磁对其结构进行了表征。并以此为原料，制备了二丙炔基双酚A醚的聚合物，利用TG-DTG研究了该聚合物的热分解动力学，并计算了动力学参数。用Kissinger法和Ozawa法求得的聚合物热分解活化能分别为166.36 kJ·mol^-1和199.90 kJ·mol^-1；用Coats-Redfern

Abstract:

Dipropargyl ether of bisphenol A was synthesized by using phase transfer catalyst and was characterized by FT-IR，1H NMR and ¹³C NMR.A polymer of dipropargyl ether of bisphenol A was prepared.TG and DTG were used to study the thermal degradation kinetics of the polymer in N₂.The kinetic parameters were calculated by methods of Kissinger and Ozawa.The results showed that the apparent degradation reaction order of the polymer of dipropargyl ether of bisphenol A was 1 in N₂ via the Coats-Redfern method.Thermal degradation activation energies of the polymer were 166.36 kJ·mol^-1 and 199.90 kJ·mol^-1 by methods of Kissinger and Ozawa respectively.The temperature of 60 s lifetime was 461℃ in N₂.

中图分类号: 

• 10.3969/j.issn.0438-1157.2011.12.037