CIESC Journal

• 能源和环境工程 • 上一篇    下一篇

饮用水深度处理系统溶解性有机物的变化与组成特性

吴义锋,吕锡武   

  1. 东南大学能源与环境学院
  • 出版日期:2011-03-05 发布日期:2011-03-05

Characteristics and constituent of dissolved organics in drinking water advanced treatment process

  • Online:2011-03-05 Published:2011-03-05

摘要:

采用混凝、沉淀、砂滤联合臭氧、生物活性炭构建饮用水深度处理系统,以黄浦江原水为研究对象,研究该系统对各类有机物的去除效能,探讨溶解性有机物在系统中的变化与组成特性。结果表明:黄浦江原水中以分子量小于3000的有机物为主,占总溶解性有机物的55.9%;常规单元、臭氧、生物活性炭对溶解性有机物的去除有功能互补性,常规单元对分子量大于10000的有机物去除率达61.1%,而对分子量小于3000的DOC去除率仅为7.9%,臭氧氧化可使难降解有机物改性为小分子量有机物,经生物活性炭单元后,分子量小于3000的DOC去除率达到28.9%;微量有机物主要通过臭氧、生物活性炭单元被去除,生物活性炭单元出水中微量有机物种类降低至30种,浓度降低67.4%,三氯甲烷生成势去除率为

Abstract:

Recently, water source pollution has become serious.Many kinds of organics have been detected in drinking water with higher concentration, and the water quality safety reduced greatly.In order to enhance the removal rate of dissolved organics in water sources, the pilot experiment containing the conventional treatment as well as the ozone and biological activated carbon filter (BACF)was reported in this paper.Taking the raw water from the Huangpu River as the sample, the characteristics and constituents of dissolved organics in the process were investigated.Results showed that the majority of organics were those with low molecular weight (MW)in the raw water, the percentage of low MW (<3000)organics reached 55.9%.In the combined treatment process, the conventional unit removed the organics with high MW (>10000)effectively, and the removal rate was up to 61.1%, while only 7.9% removal rate for low MW(<3000).The function of ozone oxidation was to modify the refractory organics into low MW organics to enhance the performance of BACF, and the removal rate of organics with MW<3000 reached 28.9% via BACF. The majority of trace organics were removed by the coordination of ozone and BACF, the types of trace organics reduced from 77 to 30, and the concentration decreased 67.4%.The trihalomethane formation potential(THMFP)was removed effectively, and the removal rate reached 73.7%.