CIESC Journal ›› 2012, Vol. 20 ›› Issue (3): 461-468.

• 香港科技大学化学与生物分子工程系戈登?麦凯教授退休纪念专刊 • 上一篇    下一篇

活性炭纤维布吸附与电热脱附挥发性有机化合物研究进展

P. L. Cloirec   

  1. Ecole Nationale Supérieure de Chimie de Rennes (ENSCR), UMR CNRS 6226 “Institut des Sciences Chimiques de Rennes”, Campus de Beaulieu, Avenue du Général Leclerc, CS 50837, 35708 Rennes cedex 07, France
  • 收稿日期:2012-02-17 修回日期:2012-04-26 出版日期:2012-06-28 发布日期:2012-04-26

Adsorption onto activated carbon fiber cloth and electrothermal desorption of volatile organic compound (VOCs): A specific review

P. L. Cloirec   

  1. Ecole Nationale Supérieure de Chimie de Rennes (ENSCR), UMR CNRS 6226 “Institut des Sciences Chimiques de Rennes”, Campus de Beaulieu, Avenue du Général Leclerc, CS 50837, 35708 Rennes cedex 07, France
  • Received:2012-02-17 Revised:2012-04-26 Online:2012-06-28 Published:2012-04-26

摘要: A general research program, focusing on activated carbon fiber cloths (ACFC) and felt for environmental protection was performed. The objectives were multiple: (i) a better understanding of the adsorption mechanisms of these kinds of materials; (ii) the specification and optimization of new processes using these adsorbents; (iii) the modeling of the adsorption of organic pollutants using both the usual and original approaches; (iv) applications of ACFC in industrial processes. The general question was: how can activated carbon fiber cloths and felts be used in air treatment processes for the protection of environment. In order to provide an answer, different approaches were adopted. The materials (ACFC) were characterized in terms of macro structure and internal porosity. Specific stud-ies were performed to get the air flow pattern through the fabrics. Head loss data were generated and modeled as a function of air velocity. The performances of ACF to remove volatile organic compounds (VOCs) were approached with the adsorption isotherms and breakthrough curves in various operating conditions. Regeneration by Joule effect shows a homogenous heating of adsorber modules with rolled or pleated layers. Examples of industrial developments were presented showing an interesting technology for the removal of VOCs, such as dichloromethane, benzene, isopropyl alcohol and toluene, alone or in a complex mixture.

关键词: activated carbon fiber cloth, adsorption, volatile organic compounds, electrothermal desorption, regeneration

Abstract: A general research program, focusing on activated carbon fiber cloths (ACFC) and felt for environmental protection was performed. The objectives were multiple: (i) a better understanding of the adsorption mechanisms of these kinds of materials; (ii) the specification and optimization of new processes using these adsorbents; (iii) the modeling of the adsorption of organic pollutants using both the usual and original approaches; (iv) applications of ACFC in industrial processes. The general question was: how can activated carbon fiber cloths and felts be used in air treatment processes for the protection of environment. In order to provide an answer, different approaches were adopted. The materials (ACFC) were characterized in terms of macro structure and internal porosity. Specific stud-ies were performed to get the air flow pattern through the fabrics. Head loss data were generated and modeled as a function of air velocity. The performances of ACF to remove volatile organic compounds (VOCs) were approached with the adsorption isotherms and breakthrough curves in various operating conditions. Regeneration by Joule effect shows a homogenous heating of adsorber modules with rolled or pleated layers. Examples of industrial developments were presented showing an interesting technology for the removal of VOCs, such as dichloromethane, benzene, isopropyl alcohol and toluene, alone or in a complex mixture.

Key words: activated carbon fiber cloth, adsorption, volatile organic compounds, electrothermal desorption, regeneration