微量酸催化麻疯树籽油制备生物柴油

Chinese Journal of Chemical Engineering ›› 2012, Vol. 20 ›› Issue (4): 740-746.

• 能源、资源与环境技术 • 上一篇下一篇

微量酸催化麻疯树籽油制备生物柴油

刘颖颖¹; 鲁厚芳¹; 蒋炜¹; 李东升¹; 刘世界²; 梁斌¹

¹ Multi-phase Mass Transfer and Reaction Engineering Laboratory, College of Chemical Engineering, Sichuan University, Chengdu 610065, China ² Department of Paper and Bioprocess Engineering, SUNY College of Environmental Science and Forestry, 1 For-estry Drive, Syracuse, NY 13210, USA

收稿日期:2011-06-20 修回日期:2011-11-05 出版日期:2012-08-28 发布日期:2011-11-05

Biodiesel production from crude Jatropha curcas L. oil with trace acid catalyst

LIU Yingying¹; LU Houfang¹; JIANG Wei¹; LI Dongsheng¹; LIU Shijie²; LIANG Bin¹

¹ Multi-phase Mass Transfer and Reaction Engineering Laboratory, College of Chemical Engineering, Sichuan University, Chengdu 610065, China ² Department of Paper and Bioprocess Engineering, SUNY College of Environmental Science and Forestry, 1 For-estry Drive, Syracuse, NY 13210, USA

Received:2011-06-20 Revised:2011-11-05 Online:2012-08-28 Published:2011-11-05

摘要/Abstract

摘要： Biodiesel produced from crude Jatropha curcas L. oil with trace sulfuric acid catalyst (0.02%-0.08% oil) was investigated at 135-184 °C. Both esterification and transesterification can be well carried out simultaneously. Factors affecting the process were investigated, which included the reaction temperature, reaction time, the molar ratio of alcohol to oil, catalyst amount, water content, free fatty acid (FFA) and fatty acid methyl ester (FAME) content. Under the conditions at 165 °C, 0.06% (by mass) H2SO4 of the oil mass, 1.6 MPa and 20︰1 methanol/oil ratio, the yield of glycerol reached 84.8% in 2 hours. FFA and FAME showed positive effect on the transesterification in certain extent. The water mass content below 1.0% did not show a noticeable effect on trans-esterification. Reaction kinetics in the range of 155 °C to 175 °C was also measured.

关键词: free fatty acids, Jatropha curcas L. oil, biodiesel, transesterification, acid catalyst

Abstract: Biodiesel produced from crude Jatropha curcas L. oil with trace sulfuric acid catalyst (0.02%-0.08% oil) was investigated at 135-184 °C. Both esterification and transesterification can be well carried out simultaneously. Factors affecting the process were investigated, which included the reaction temperature, reaction time, the molar ratio of alcohol to oil, catalyst amount, water content, free fatty acid (FFA) and fatty acid methyl ester (FAME) content. Under the conditions at 165 °C, 0.06% (by mass) H2SO4 of the oil mass, 1.6 MPa and 20︰1 methanol/oil ratio, the yield of glycerol reached 84.8% in 2 hours. FFA and FAME showed positive effect on the transesterification in certain extent. The water mass content below 1.0% did not show a noticeable effect on trans-esterification. Reaction kinetics in the range of 155 °C to 175 °C was also measured.

Key words: free fatty acids, Jatropha curcas L. oil, biodiesel, transesterification, acid catalyst

刘颖颖, 鲁厚芳, 蒋炜, 李东升, 刘世界, 梁斌. 微量酸催化麻疯树籽油制备生物柴油[J]. Chinese Journal of Chemical Engineering, 2012, 20(4): 740-746.

LIU Yingying, LU Houfang, JIANG Wei, LI Dongsheng, LIU Shijie, LIANG Bin. Biodiesel production from crude Jatropha curcas L. oil with trace acid catalyst[J]. Chin.J.Chem.Eng., 2012, 20(4): 740-746.

[1]	蔡贾林, 崔现宝, 杨志才. Simulation for Transesterification of Methyl Acetate and n-Butanol in a Reactive and Extractive Distillation Column Using Ionic Liquids as Entrainer and Catalyst[J]. CIESC Journal, 2011, 19(5): 754-762.
[2]	舒庆, 高继贤, 廖玉会, 王金福. Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst[J]. CIESC Journal, 2011, 19(1): 163-168.
[3]	李政, 邓利, 鲁吉珂, 郭小雷, 杨自信, 谭天伟. Enzymatic Synthesis of Fatty Acid Methyl Esters from Crude Rice Bran Oil with Immobilized Candida sp. 99-125[J]. CIESC Journal, 2010, 18(5): 870-875.
[4]	周诚, 王存文, 王为国, 吴元欣, 喻发全, 池汝安, 张俊峰. Continuous Production of Biodiesel from Soybean Oil Using Supercritical Methanol in a Vertical Tubular Reactor:I.Phase Holdup and Distribution of Intermediate Product along the Axial Direction[J]. CIESC Journal, 2010, 18(4): 626-629.
[5]	龙涛, 邓岳锋, 甘树才, 陈继. Application of Choline Chloride·xZnCl₂ Ionic Liquids for Preparation of Biodiesel[J]. CIESC Journal, 2010, 18(2): 322-327.
[6]	范燕平, 王庆印, 杨先贵, 姚洁, 王公应. Synthesis of Didodecyl Carbonate via Transesterification Catalyzed by KF/MgO[J]. CIESC Journal, 2009, 17(5): 883-886.
[7]	甘孟瑜, 潘登, 马利, 岳恩, 洪建兵. The Kinetics of the Esterification of Free Fatty Acids in Waste Cooking Oil Using Fe₂(SO₄)₃/C Catalyst[J]. CIESC Journal, 2009, 17(1): 83-87.
[8]	冯冬梅, 左宜赞, 王德峥, 王金福. Steam Reforming of Dimethyl Ether over Coupled Catalysts of CuO-ZnO-Al₂O₃-ZrO₂ and Solid-acid Catalyst[J]. CIESC Journal, 2009, 17(1): 64-71.
[9]	田华, 李春义, 杨朝合, 山红红. Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins[J]. CIESC Journal, 2008, 16(3): 394-400.
[10]	梁学正, 高珊, 王雯娟, 程文萍, 杨建国. Ketalization of Catechol with Carbonyl Compounds Catalyzed by Metal p-Toluenesulfonate as Biphasic Acid Catalyst[J]. CIESC Journal, 2008, 16(1): 124-127.
[11]	张丹, 王庆印, 姚洁, 王越, 曾毅, 王公应. 碱金属化合物催化同时合成碳酸二甲酯和聚对苯二甲酸乙二醇酯[J]. CIESC Journal, 2007, 15(5): 772-774.
[12]	秦吉臣, 谢小莉, 曹贤武, 瞿金平. 聚碳酸酯连续熔融酯交换过程的反应闪蒸模拟[J]. CIESC Journal, 2007, 15(1): 51-62.
[13]	Nora Alejandra Comelli,　Omar Masini,　Alfredo L’azaro Carrascull,　Esther Natalia Ponzi, Marta Isabel Ponzi. Production of Camphene by Isomerization Reaction on Sulfated ZrO₂[J]. CIESC Journal, 2000, 8(1): 64-67.

微量酸催化麻疯树籽油制备生物柴油

Biodiesel production from crude Jatropha curcas L. oil with trace acid catalyst

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 13

编辑推荐

Metrics

本文评价