关键词: 全氟甲基乙烯基醚, 四氟乙烯法, 热解法, 还原法, 六氟环氧丙烷法

Abstract: Perfluoromethyl perfluorovinyl ether (PMVE) as an important monomer has been widely used in the synthysis of the new fluororubber and fluoroplastics. The synthesis methods of PMVE are reviewed and classified into：process with tetrafluoroethylene，pyrolysis，reduction and process with hexafluoropropylene oxide. Moreover，the progress of PMVE processing is reviewed，and the advantages and disadvantages of these synthesis methods are analyzed. Improvement of the new lab-scale techniques may be an important way for commercialization of PMVE.

Key words: perfluoromethyl perfluorovinyl ether(PMVE), tetrafluoroethylene, pyrolysis, reduction, hexafluoropropylene oxide