两种封端聚醚大单体及其共聚物制备与阻磷酸钙垢应用

doi:10.3969/j.issn.0438-1157.2013.07.051

化工学报 ›› 2013, Vol. 64 ›› Issue (7): 2687-2695.DOI: 10.3969/j.issn.0438-1157.2013.07.051

• 材料化学工程与纳米技术 • 上一篇下一篇

两种封端聚醚大单体及其共聚物制备与阻磷酸钙垢应用

符嫦娥^1,2,3, 胡大华¹, 韩承辉¹, 刘海霞¹, 仓理², 周钰明³

1. 江苏开放大学, 江苏南京 210036;
2. 南京化工职业技术学院, 江苏南京 210048;
3. 东南大学化学化工学院, 江苏南京 211189

收稿日期:2012-08-15 修回日期:2013-04-13 出版日期:2013-07-05 发布日期:2013-07-05
通讯作者: 周钰明
作者简介:符嫦娥(1971- ),女,博士,副教授。
基金资助:
国家自然科学基金项目(51278253);江苏省自然科学基金项目(BK2011691)。

Synthesis of capped polyether macromonomers and their copolymers as antiscalants for calcium phosphate

FU Chang'e^1,2,3, HU Dahua¹, HAN Chenghui¹, LIU Haixia¹, CANG Li², ZHOU Yuming³

1. Jiangsu Open University, Nanjing 210036, Jiangsu, China;
2. Nanjing College of Chemical Technology, Nanjing 210048, Jiangsu, China;
3. School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, Jiangsu, China

Received:2012-08-15 Revised:2013-04-13 Online:2013-07-05 Published:2013-07-05
Supported by:
supported by the National Natural Science Foundation of China (51278253)and the Natural Science Foundation of Jiangsu Province (BK2011691).

摘要/Abstract

摘要： 采用烯丙基聚乙二醇单醚APEO10为原料制备了大分子单体磺酸盐封端聚醚APES10和羧酸盐封端聚醚APEC10并分别与小分子单体丙烯酸AA聚合生成两种聚羧酸类阻垢剂AA/APES10和AA/APEC10,用红外光谱、核磁共振对其结构进行了表征。实验确定了聚合反应单体最佳质量比为m(APES10):m(AA)=1:1,m(APEC10):m(AA)=2:3。通过静态阻垢实验对比了两种聚合物的阻磷酸钙垢性能。结果表明,合成的两种阻垢剂AA/APES10和AA/APEC10在临界值6 mg·L^-1时阻磷酸钙垢率分别为92%、100%,但羧酸盐封端聚醚大单体合成的阻垢剂AA/APEC10阻磷酸钙垢能力优于磺酸盐封端聚醚大单体合成的阻垢剂,且聚合物AA/APEC10只含碳、氢、氧、钠4种元素,无氮、磷污染,可以充当循环水用环保型阻磷酸钙垢阻垢剂。

关键词: 聚羧酸阻垢剂, 封端聚醚大单体, 磷酸钙, 循环水

Abstract: Capped polyether macromonomers APES10 and APEC10 were synthesized from allyl polyethylene glycol sole ether APEO10,and their polycarboxylic acid type copolymers AA/APES10,AA/APEC10 as antiscalants were prepared from small molecule monomers acrylic acid AA.The products were characterized by FT-IR and ¹H NMR and the performance of their copolymers of calcium phosphate inhibition was evaluated by the static scale-inhibiting method.The studies indicated that when mass ratio of APES10 to AA was 1:1,APEC10 to AA was 2:3,both AA/APEC10 and AA/APES10 had much better ability to inhibit the precipitation of calcium phosphate than other mass ratios.It was also shown that both AA/APEC10 and AA/APES10 had superior ability to inhibit the precipitation of calcium phosphate when the dosage was 6 mg·L^-1,approximately showing 100%,92% inhibition,respectively. While compared to that of AA/APES10,AA/APEC10 had superior ability to control calcium-phosphate deposition.Furthermore,the synthesized AA/APEC10 is an environmentally friendly antiscalant,only containing four elements of carbon (C),hydrogen (H),oxygen (O),sodium (Na),without phosphorous (P)and nitrogen (N).AA/APEC10 is an excellent performance non-phosphorus inhibitor for calcium phosphate scaling in industrial recycling water systems.

Key words: polycarboxylic acid type antiscalant, capped polyether macromonomer, calcium phosphate, recycling water

中图分类号:

TG174

符嫦娥, 胡大华, 韩承辉, 刘海霞, 仓理, 周钰明. 两种封端聚醚大单体及其共聚物制备与阻磷酸钙垢应用[J]. 化工学报, 2013, 64(7): 2687-2695.

FU Chang'e, HU Dahua, HAN Chenghui, LIU Haixia, CANG Li, ZHOU Yuming. Synthesis of capped polyether macromonomers and their copolymers as antiscalants for calcium phosphate[J]. CIESC Journal, 2013, 64(7): 2687-2695.

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两种封端聚醚大单体及其共聚物制备与阻磷酸钙垢应用

Synthesis of capped polyether macromonomers and their copolymers as antiscalants for calcium phosphate

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