化工学报 ›› 2009, Vol. 60 ›› Issue (9): 2404-2408.

• 材料化学工程与纳米技术 • 上一篇    

微波等离子体法合成重油残渣基定向纳米碳薄膜

杨永珍,郭明聪,刘旭光,许并社   

  1. 新材料界面科学与工程教育部重点实验室(太原理工大学); 太原理工大学材料科学与工程学院;太原理工大学化学化工学院
  • 出版日期:2009-09-05 发布日期:2009-09-05

Preparation of oriented carbon films from heavy oil residue by microwave plasma

YANG Yongzhen,GUO Mingcong,LIU Xuguang,XU Bingshe   

  • Online:2009-09-05 Published:2009-09-05

摘要: 以重油残渣为原料,采用微波等离子法制备了一种结构新颖的定向纳米碳薄膜材料。经场发射扫描电子显微镜、高分辨透射电子显微镜分析,结果表明:产物纯度较高,外观呈条状麦穗形,各条状物平行排列形成定向阵列,最大宽度约为65nm,长度可达900nm左右;麦穗的主干表层和穗片晶化程度较好,层与层之间清晰可见,中心部位为非晶态,可能是产物经历了由外向内的生长过程,重油残渣中的重金属Ni、Fe等对其生长起了一定的催化作用。

关键词:

重油残渣, 微波等离子体法, 定向纳米碳薄膜

Abstract:

Oriented carbon films with novel structure were prepared by microwave plasma from heavy oil residue.The prepared films were characterized by field emission scanning electron microscopy, high resolution transmission electron microscopy, X-ray powder diffraction and Raman spectroscopy.The products were formed with high purity, and oriented as the shape of a strip-like wheat spike.The outer layers of the spike have a higher degree of crystallization, the maximum width and length are about 65 nm and 900 nm, respectively, while the central parts are amorphous.It was suggested that the products experienced a process from outer to inner growth.Some metals existed in the deoiled asphalt, such as Ni and Fe, may contribute as catalyst to the aligned carbon film growth.

Key words:

重油残渣, 微波等离子体法, 定向纳米碳薄膜