CIESC Journal

• 化工学报 •    下一篇

甲酸甲酯直接水解法制甲酸的研究(Ⅰ)──反应动力学

陆乃宸,张克城,谭丕亨,杨天祝,吴烈钧   

  1. 山东省化工研究院!济南250014,山东省化工研究院!济南250014,山东省化工研究院!济南250014,山东省化工研究院!济南250014,山东省化工研究院!济南250014
  • 出版日期:1998-06-25 发布日期:1998-06-25

STUDIES ON DIRECT HYDROLYSIS 0F METHYL FORMATE INTO FORMIC ACID(I)──REACTION KINETICS

Lu Naichen;Zhang Kecheng;Tan Piheng;Yang Tianzhu;Wu Liejun(Shandong Research of Chemical Industry,Jinan 250014)   

  • Online:1998-06-25 Published:1998-06-25

摘要: 在80℃~120℃之间对甲酸甲酯水解生成甲酸的反应动力学进行了研究,并与文献的研究结果作了比较和讨论.所得反应速率方程可表示为式中;平衡常数K则可引用文献的经验关联式.

Abstract: The reaction kinetics on the direct hydrolysis of methyl fomate into formic acid at temperatures of 8℃~120℃ has been investigated experimentally and compared with literature data.The reaction rate equation can be expressed as follows in which k=24556_(exp)-6268/T)and the equilibrium constant K may be calculated by an empirical formula published in literature.

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