CIESC Journal ›› 2003, Vol. 54 ›› Issue (7): 942-945.
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TAO Jingguang;LIAO Zhaoshu;LUO Huiqian;PENG Xiying
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陶景光;廖兆曙;罗慧倩;彭喜英
Abstract: The ferrite catalyst synthesized under magnetic field has a crystalline structure of spinel type FexO,with 0.75≤x≤0.85.The magnetic field can impel more Fe2+ to occupy the octahedral site,so Fe/O atom ratio, the residual magnetron and the crystal defects are increased.As a result,the spinel ferrite catalyst can increase the catalytic redox reaction rate such as decomposition of H2O2.
Key words: 铁氧体催化剂, 双氧水分解, 催化反应动力学, 高分辨分析电子显微镜(HRAEM), 电子能量损失谱(EELS)
摘要: 通过双氧水催化分解反应动力学研究,显示磁化合成铁氧体具有较高的催化速率.利用高分辨分析电镜和电子能量损失谱测试了其显微形貌、化学组成和微区晶体结构,探讨了催化作用机理.
关键词: 铁氧体催化剂, 双氧水分解, 催化反应动力学, 高分辨分析电子显微镜(HRAEM), 电子能量损失谱(EELS)
TAO Jingguang, LIAO Zhaoshu, LUO Huiqian, PENG Xiying. SYNTHESIS OF FERRITE CATALYST UNDER MAGNETIC FIELD AND ITS INFLUENCE ON HYDROGEN PEROXIDE DECOMPOSITION[J]. CIESC Journal, 2003, 54(7): 942-945.
陶景光, 廖兆曙, 罗慧倩, 彭喜英. 铁氧体催化剂磁性合成及其对双氧水分解反应的影响 [J]. 化工学报, 2003, 54(7): 942-945.
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