Abstract: The equations relating the adsorption equilibrium constant and reactionrate constants on a single catalyst pellet to measureable properties of pulse-response experiments were derived by means of statistical moment theory. Under atmospheric pressure and at a temperature upto 340℃ the effective diffusivities and the adsorption equilibrium constants oi carbon monoxide and the rate constants for shift reaction CO + H2O = CO2 + H2 on a B110 catalyst pellet were measured by using ordinary thermal conductivity cell(TCC). It has been proved to be a new and valuable technique for determining the kinetic parameters of gas-solid heterogeneous catalytic reaction.

摘要： 运用统计矩理论推导出催化剂颗粒内气体吸附常数、有效扩散系数和反应速率常数与实验矩之间的关联式.在常压及高至340℃的温度下,用常规的热导池鉴定器测定了Co在B110催化剂中的有效扩散系数、吸附平衡常数以及变换反应CO十H_2O=H_2十CO_2的反应速度常数.它为化学反应工程基础研究提供了一种新型的、有效实用的实验技术.